journal article·2020-02-05

Zeolitic Vanadomolybdates as High-Performance Cathode-Active Materials for Sodium-Ion Batteries

Zhenxin Zhang, Heng Wang, Hirofumi Yoshikawa, Daiju Matsumura, Syuya Hatao, Satoshi Ishikawa, Wataru Ueda

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Abstract

Developing new cathode-active materials for rechargeable batteries is important to fulfill the growing demands of energy transformation, storage, and utilization. Zeolitic transition-metal oxides based on vanadomolybdate, constructed by pentagon metal–oxygen clusters as building blocks and metal ions as linkers in a trigonal symmetry, are good candidates for cathodes of Na rechargeable batteries. The material is activated via amorphization of the crystal structure in the ab plane during discharging process, keeping the molecular structure of the building blocks stable, which causes high specific capacity and good cycle performance.
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Research context

OpenAlex topics: Advancements in Battery Materials · Polyoxometalates: Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Material Science and Chemical Engineering, Ningbo University, Fenghua road 818, Ningbo, Zhejiang 315211, P. R. China

School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China

School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

Materials Sciences Research Center, Japan Atomic Energy Agency, Sayo-gun, Hyogo 679-5148, Japan

Faculty of Engineering, Kanagawa University, Rokkakubashi, Kanagawa-ku, Yokohama-shi, Kanagawa 221-8686, Japan

Funding

Natural Science Foundation of Ningbo · Japan Society for the Promotion of Science · National Natural Science Foundation of China

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