journal article·2018-01-10

Extraordinary Porous Few-Layer Carbons of High Capacitance from Pechini Combustion of Magnesium Nitrate Gel

Meng Qian, Yuan Wang, Feng Xu, Wei Zhao, Tianquan Lin, Fuqiang Huang

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Abstract

Highly capacitive carbons are viewed as promising commercial materials for supercapacitors, but few species satisfy the requirements of high capacitance and low cost. Here, we demonstrate an extraordinary porous few-layer carbon by facile Pechini combustion of magnesium nitrate gel, which combined salicylic acid as a complexing agent with magnesium nitrate as an inorganic metal salt. The as-synthesized carbon material delivers a capacitance of 415 F g –1, mostly stemming from a large specific surface area (∼1312 m 2 g –1 ), a fluent channel for transport of the electrolyte, as well as electrochemical redox reactions at O,N-associated active sites. Such porous few-layer carbons may accelerate the adoption of carbon-based supercapacitors for commercial high-power energy storage applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049, China

Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Funding

Ministry of Science and Technology of the People's Republic of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · Chinese Academy of Sciences

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