journal article·2014-05-28

Silicon Interfacial Passivation Layer Chemistry for High-k/InP Interfaces

Hong Dong, Wilfredo Cabrera, Xiaoye Qin, Barry Brennan, Dmitry Zhernokletov, Christopher L. Hinkle, Jiyoung Kim, Yves J. Chabal, Robert M. Wallace

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Abstract

The interfacial chemistry of thin (1 nm) silicon (Si) interfacial passivation layers (IPLs) deposited on acid-etched and native oxide InP(100) samples prior to atomic layer deposition (ALD) is investigated. The phosphorus oxides are scavenged completely from the acid-etched samples but not completely from the native oxide samples. Aluminum silicate and hafnium silicate are possibly generated upon ALD and following annealing. The thermal stability of a high-k/Si/InP (acid-etched) stack are also studied by in situ annealing to 400 and 500 °C under ultrahigh vacuum, and the aluminum oxide/Si/InP stack is the most thermally stable. An indium out-diffusion to the sample surface is observed through the Si IPL and the high-k dielectric, which may form volatile species and evaporate from the sample surface.
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Research context

OpenAlex topics: Semiconductor materials and devices · Semiconductor materials and interfaces · Integrated Circuits and Semiconductor Failure Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080, United States

Department of Physics, University of Texas at Dallas, Richardson, Texas 75080, United States

Funding

National Science Foundation

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