Scalable Solution Processing MoS₂ Powders with Liquid Crystalline Graphene Oxide for Flexible Freestanding Films with High Areal Lithium Storage Capacity

Freestanding flexible electrodes with high areal mass loading are required for the development of flexible high-performance lithium-ion batteries (LIBs). Currently they face the challenge of low mass loading due to the limited concentrations attainable in processable dispersions. Here, we report a simple low-temperature hydrothermal route to fabricate flexible layered molybdenum disulfide (MoS2)/reduced graphene oxide (MSG) films offering high areal capacity and good lithium storage performance. This is achieved using a self-assembly process facilitated by the use of liquid crystalline graphene oxide (LCGO) and commercial MoS2 powders at a low temperature of 70 °C. The amphiphilic properties of ultralarge LCGO nanosheets facilitates the processability of large-size MoS2 powders, which is otherwise nondispersible in water. The resultant film with an areal mass of 8.2 mg cm–2 delivers a high areal capacity of 5.80 mAh cm–2 (706 mAh g–1) at 0.1 A g–1. This simple method can be adapted to similar nondispersible commercial battery materials for films fabrication or production of more complicated constructs via advanced fabrication technologies.