Robust and Transparent Lossless Directional Omniphobic Ultra-Thin Sticker-Type Film with Re-entrant Micro-Stripe Arrays

Directional droplet-sliding control without wetting the surface is immensely required in advanced surface engineering, including biological and chemical analyses or green technology. However, the development of robust and transparent thin sticker-type directional omniphobic films for portable usage in smart microfluidic platforms is rare. In this study, we report a novel perfluoropolyether (PFPE) directional omniphobic film (PDOF). The PDOF is a robust and transparent ultra-thin sticker-type film that can control the anisotropic sliding of various liquid droplets on the surface. The PFPE is a chemically stable and turgid material compared to polydimethylsiloxane (PDMS), which is often used to fabricate liquid-repellent thin films. A well-designed fabrication criterion through adhesion engineering in the soft-molding process was developed using the PFPE to obtain a PDOF with a thickness of 56 μm, with re-entrant micro-stripe structures on the surface. The fabricated PDOF showed intriguing liquid sliding properties based on the direction and spacing of the microstructures. This aspect is defined as an anisotropic factor.