DataVXACS Applied Materials & InterfacesPaper
journal article·2022-05-11

Fabrication of Single-Particle Microelectrodes and Their Electrochemical Properties

Yuanyuan Ren, Limin Liu, Zhen Wang, De Li, Yong Chen

ACS Applied Materials & Interfaces· Volume 14· Issue 18
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Source abstract

Abstract

Compared with traditional centimeter-level electrodes, microelectrodes exhibit a small reaction area, high sensitivity, fast mass transfer rate, and low polarization current. However, current microelectrode preparation processes are very complicated and costly. Herein, we proposed a facile and universal method for fabricating single-particle microelectrodes. In the precursor solution, polyvinyl alcohol and ammonia were introduced as the polymeric binder and pore-forming agent, respectively. Through spaying-drying-sintering processes, the single-particle microelectrodes were successfully prepared for Li4Ti5O12 (LTO), LiCrTiO4 (LCTO), and LiFePO4/C (LFP/C), which showed excellent electrochemical properties. Furthermore, the single-particle microelectrode can be adopted to study the electrochemical oscillations of Li-ion batteries and assemble a full-cell microbattery as a potential next-generation microscale power source.
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Research context

Energy storagePolymersCeramics & glasses

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Marine Resource Utilization in South China Sea, Key Laboratory of Research on Utilization of Si-Zr-Ti Resources of Hainan Province, School of Materials Science and Engineering, Hainan University, Haikou 570228, China

Guangdong Key Laboratory for Hydrogen Energy Technologies; School of Materials Science and Hydrogen Energy, Foshan University, Foshan 528000, China

Funding

Key Research and Development Project of Hainan Province · Natural Science Foundation of Hainan Province · Hainan University · National Natural Science Foundation of China · Graduate Innovation Research Project of Hainan · Guangdong Key Laboratory for Hydrogen Energy Technologies · Guangdong Province

References (35)

Show source-provided references
1. 10.1039/c9ee03219c10.1039/c9ee03219c ↗
2. 10.3390/s2115504110.3390/s21155041 ↗
3. 10.1016/j.nanoen.2020.10566610.1016/j.nanoen.2020.105666 ↗
4. 10.1109/access.2019.293768910.1109/access.2019.2937689 ↗
5. 10.1126/sciadv.aat062610.1126/sciadv.aat0626 ↗
6. 10.1021/acsenergylett.1c0076810.1021/acsenergylett.1c00768 ↗
7. 10.1002/adma.20200749710.1002/adma.202007497 ↗
8. 10.1021/acs.jpcc.0c0288110.1021/acs.jpcc.0c02881 ↗
9. 10.1039/d1tc01618k10.1039/d1tc01618k ↗
10. 10.1016/j.snb.2019.03.04510.1016/j.snb.2019.03.045 ↗
11. 10.1039/c8ee00001h10.1039/c8ee00001h ↗
12. 10.1016/j.jelechem.2019.01.06110.1016/j.jelechem.2019.01.061 ↗
13. 10.1016/j.electacta.2018.09.05010.1016/j.electacta.2018.09.050 ↗
14. 10.1016/j.jpowsour.2020.22860010.1016/j.jpowsour.2020.228600 ↗
15. 10.1021/acsomega.0c0066610.1021/acsomega.0c00666 ↗
16. 10.1021/acs.chemmater.5b0202710.1021/acs.chemmater.5b02027 ↗
17. 10.1021/acssuschemeng.7b0256710.1021/acssuschemeng.7b02567 ↗
18. 10.1039/d1gc03333f10.1039/d1gc03333f ↗
19. 10.1039/d0dt01719a10.1039/d0dt01719a ↗
20. 10.1039/c2jm32673f10.1039/c2jm32673f ↗
21. 10.1038/srep2594210.1038/srep25942 ↗
22. 10.1016/j.ssi.2010.09.05610.1016/j.ssi.2010.09.056 ↗
23. 10.1002/adma.20100204510.1002/adma.201002045 ↗
24. 10.1016/j.electacta.2013.11.10610.1016/j.electacta.2013.11.106 ↗
25. 10.1039/d0ta09212f10.1039/d0ta09212f ↗
26. 10.1016/j.cej.2021.13219610.1016/j.cej.2021.132196 ↗
27. 10.1021/acsami.0c0827010.1021/acsami.0c08270 ↗
28. 10.1007/s11581-018-2738-510.1007/s11581-018-2738-5 ↗
29. 10.1016/j.jpowsour.2019.03.06810.1016/j.jpowsour.2019.03.068 ↗
30. 10.1016/s1872-5805(20)60487-510.1016/s1872-5805(20)60487-5 ↗
31. 10.1016/j.joule.2018.03.01410.1016/j.joule.2018.03.014 ↗
32. 10.1039/c9cc90335f10.1039/c9cc90335f ↗
33. 10.1021/acs.jpcc.1c0382910.1021/acs.jpcc.1c03829 ↗
34. 10.1016/j.ensm.2021.01.00210.1016/j.ensm.2021.01.002 ↗
35. 10.1002/adma.20200553110.1002/adma.202005531 ↗