journal article·2024-05-01Open access

Gold(I)–Thiolate Coordination Polymers as Multifunctional Materials: The Case of Au(I)–p-Fluorothiophenolate

Shefali Vaidya, Saly Hawila, Fan Zeyu, Tuhin Khan, Alexandra Fateeva, François Toche, Rodica Chiriac, Anne Bonhommé, Gilles Ledoux, Sébastien Lebègue, Jeongmin Park, Won June Kim, Juejing Liu, Xiaofeng Guo, Adel Mesbah, Satoshi Horike, Aude Demessence

ACS Applied Materials & Interfaces· Volume 16· Issue 17

Abstract

Gold–sulfur interaction has vital importance in nanotechnologies and material chemistry to design functional nanoparticles, self-assembled monolayers, or molecular complexes. In this paper, a mixture of only two basic precursors, such as the chloroauric acid (HAu(III)Cl 4 ) and a thiol molecule ( p -fluorothiophenol ( p -HSPhF)), are used for the synthesis of gold(I)–thiolate coordination polymers. Under different conditions of synthesis and external stimuli, five different functional materials with different states of [Au(I)( p -SPhF)] n can be afforded. These gold–thiolate compounds are (i) red emissive, flexible, and crystalline fibers; (ii) composite materials made of these red emissive fibers and gold nanoparticles; (iii) amorphous phase; (iv) transparent glass; and (v) amorphous-to-crystalline phase-change material associated with an ON/OFF switch of luminescence. The different functionalities of these materials highlight the great versatility of the gold(I) thiolate coordination polymers with easy synthesis and diverse shaping that may have great potential as sustainable phosphors, smart textiles, sensors, and phase change memories.
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Research context

OpenAlex topics: Organometallic Compounds Synthesis and Characterization · Nanocluster Synthesis and Applications · Catalysis and Hydrodesulfurization Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University Claude Bernard Lyon 1, CNRS, IRCELYON – UMR 5256, Villeurbanne 69100, France

Institute of Experimental and Applied Physics, Czech Technical University in Prague, Prague 110 00, Czech Republic

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Institute of Macromolecular Chemistry, Czech Academy of Sciences, Prague 162 00, Czech Republic

University Claude Bernard Lyon 1, CNRS, LMI - UMR 5615, Villeurbanne 69622, France

University Claude Bernard Lyon 1, CNRS, ILM - UMR 5306, Villeurbanne 69622, France

University of Lorraine, CNRS, LPCT - UMR 7019, Vandœuvre-lès-Nancy 54506, France

Department of Biology and Chemistry, Changwon National University, Gyeongsangnam-do 51140, South Korea

Department of Chemistry, Washington State University, Pullman, Washington 99164, United States

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand

Funding

Agence Nationale de la Recherche · Japan Society for the Promotion of Science · Centre National de la Recherche Scientifique · French-Korean program STAR · DKRVO, Czech Republic

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