journal article·2022-05-25Open access

Attenuation of Photoelectron Emission by a Single Organic Layer

Thorsten Wagner, Grażyna Antczak, Michael Györök, Agata Sabik, Anna Volokitina, Franciszek Gołek, Peter Zeppenfeld

ACS Applied Materials & Interfaces· Volume 14· Issue 20

Abstract

We report an in situ study of the thin-film growth of cobalt-phthalocyanine on Ag(100) surfaces using photoelectron emission microscopy (PEEM) and the Anderson method. Based on the Fowler-DuBridge theory, we were able to correlate the evolution of the mean electron yield acquired with PEEM for coverages up to two molecular layers of cobalt-phthalocyanine to the global work function changes measured with the Anderson method. For coverages above two monolayers, the transients measured with the Anderson method and those obtained with PEEM show different trends. We exploit this discrepancy to determine the inelastic mean free path of the low-energy electrons while passing through the third layer of CoPc.
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Research context

OpenAlex topics: Electron and X-Ray Spectroscopy Techniques · Surface and Thin Film Phenomena · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Johannes Kepler University, Institute of Experimental Physics, Surface Science Division, Altenberger Strasse 69, 4040 Linz, Austria

University of Wroclaw, Institute of Experimental Physics, Pl. M. Borna 9, 50-204 Wroclaw, Poland

Funding

Austrian Science Fund · OeAD-GmbH

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