journal article·2023-08-30

Metal–Organic Frameworks/Graphdiyne/Copper Foam Composite Membranes for Catalytic Applications

Yanjie Wu, Yucheng Yang, Zhihai Ke

ACS Applied Materials & Interfaces· Volume 15· Issue 34
Publisher page

Abstract

Graphdiyne (GDY) with a three-dimensional network structure was synthesized on a copper foam (CF) via an in situ Glaser-Hay coupling reaction. A metal-organic framework/GDY composite membrane was designed and synthesized for the first time. CF serves as a template and catalyst for the directed polymerization of GDY membranes. The catalytic activities of HKUST-1/GDY/CF membrane in wet peroxide oxidation of phenol, oxidation of benzyl alcohol, and ring opening of epoxide were studied. The composite membrane has the advantages of appropriateness for continuous operation, simple use process, easy recycling, high catalytic efficiency, etc. It was found that the incorporation of GDY can facilitate electron transfer and effectively improve the catalytic activity of HKUST-1 in membrane catalysis.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen 518172, Guangdong, China

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China

Funding

Basic and Applied Basic Research Foundation of Guangdong Province · Guangdong Provincial Pearl River Talents Program · Shenzhen Key Laboratory Fund · Chinese University of Hong Kong

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