Dual Challenge–Response Systems of a Three-Dimensional “Bionic” Fluorescent Physically Unclonable Function Label

Inspired by the light and dark variations observed in natural cloud clusters under sunlight, we propose a three-dimensional (3D) “bionic” fluorescent physically unclonable function (PUF) label. The minimalist preparation process eliminates the need for expensive traditional instruments, thus offering new insight into the widespread adoption of 3D PUF labels. The Eu(CCA) 3 (H 2 O) 2 powder, which is the first to propose its secondary building unit, was chosen as the fluorescent material. Its 3D morphology is preserved in the resin to mimic cloud-like structures. Furthermore, the luminescent properties are elucidated through experimental tests and first-principles calculations. To overcome the coding capacity limitation of traditional two-dimensional (2D) fluorescent PUF labels, a dual challenge–response system model is proposed. The shallow and deep models provide anticounterfeiting information from macro and micro perspectives, respectively. This successfully increases the encoding capacity from 2 10×10 to 2 100×10000 for a 10 × 10 pixel binary code. Therefore, 3D “bionic” fluorescent PUF labels strike a balance between the simple usage of PUF labels and enhanced label security.