journal article·2022-07-13

Ion Motor as a New Universal Strategy for the Boosting the Performance of Zn-Ion Batteries

Lulu Chai, Junqing Pan, Xiaoyang Zhu, Yanzhi Sun, Xiaoguang Liu, Wei Li, Jinjie Qian, Xifei Li, Xueliang Sun

ACS Applied Materials & Interfaces· Volume 14· Issue 27
Publisher page

Abstract

The quiescent electrolyte causes serious concentration polarization and dendrite problems during the charging and discharging of the battery, which restricts the development of metal secondary batteries and flow batteries. Herein, we report a new concept of ion motors, with which the directional driving and uniformity of the electrolyte are realized to eliminate the concentration polarization and dendritic phenomenon for secondary metal batteries and flow batteries without additional external energy. In this study, a dendrite-free secondary metal battery with ion motors is constructed to eliminate a considerable concentration polarization voltage by a tiny induced counter electromotive force generated by Lorentz force, significantly improving the output power and energy efficiency of the battery. An actual pump-free flow battery with an ion motor is also assembled, which overcomes the problems of low energy efficiency and the complex structure caused by the traditional flow battery requiring 1-2 pumps to drive the electrolyte. The efficiency of ion motors to drive the electrolyte is hundreds of times higher than that of the mechanical pump. Therefore, the ion motor provides a universal strategy for designing more pump-free flow batteries and metal secondary batteries without the risk of dendrites in the future.
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Research context

OpenAlex topics: Advanced battery technologies research · Advanced Battery Technologies Research · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

Department of Engineering Technology and Texas Center for Superconductivity, University of Houston, Houston, Texas 77204, United States

Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325000, China

Xi’an Key Laboratory of New Energy Materials and Devices, Institute of Advanced Electrochemical Energy & School of Materials Science and Engineering, Xi’an University of Technology, Xi’an, Shanxi 710048, China

Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5 B9, Canada

Funding

Ministry of Science and Technology of the People's Republic of China · Central University Basic Research Fund of China · National Natural Science Foundation of China

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