Light-Induced Programmable 2D Ordered Patterns Based on a Hyperbranched Poly(ether amine) (hPEA)-Functionalized Graphene Film

Dynamic complex surface topography with ordered and tunable morphologies, which can provide on-demand control of surface properties to realize smart surfaces, is gaining much attention yet remains challenging in terms of fabrication. Here, a facile, robust, and controllable method is demonstrated to fabricate programmable two-dimensional (2D) ordered patterns with multiresponsive 2D ultrathin materials, comprised of anthracene-capped hyperbranched poly(ether amine) (hPEA-AN)-functionalized graphene (hPEA-AN@G). By combining the stimuli-responsiveness and UV sensitivity of hPEA-AN and excellent out-of-plane deformation and NIR-to-thermal conversion of graphene, the process of "writing/uploading" initial information is conducted through the initial exposure to 365 nm UV light to generate the 2D ordered pattern first; second, inducing swelling strain via moisture to create the hierarchical topographic pattern (orderly oriented pattern) is the process of "modification and erasable rewriting"; third, alternating NIR or 254 nm UV light blanket exposure are the two ways of erasing the information. Consequently, taking advantage of the multiresponsive dynamic wrinkling/ordered patterning, we can program globally 2D ordered surface patterns with diverse morphologies on demand and manipulate the resulted surface properties as desired.