One-Step Water-Induced Phase Separation Simultaneously Triggering Polymer Solidification and Polyelectrolyte Complexation for Porous Ultrafiltration Membranes

Functional additives have been widely utilized for the membrane structure modulation and performance improvement during the nonsolvent-induced phase separation process, but the resulted membranes easily suffer from additives’ inhomogeneous dispersity and compatibility with the polymer matrix. Herein, a facile and robust strategy, i.e., one-step water-induced phase separation, was proposed for the preparation of polyelectrolytes-contained composite membranes. Polyanion (dopamine modified polyacrylic acid) and polycation (quaternized chitosan paired with bis(trifluoromethane-sulfonyl)imide) were first premixed in dimethyl sulfoxide and used as polyelectrolyte additives in a polysulfone (PSF) solution, and then a uniform PSF-based casting solution was readily obtained. During the solvent–water exchange process, polymer solidification and polyelectrolyte complexation were simultaneously triggered, in situ generating a polyelectrolyte complex fixed within the membrane matrix. Ultrafiltration membranes with hierarchical structures were notably tailored through altering the concentration, molecular weight, and type of polyelectrolytes. The obtained membrane exhibited a water flux of 672 L·m–2·h–1, three times over the raw PSF membrane, while almost maintaining high bovine serum albumin (BSA) rejection. This work paves a straightforward and convenient path for the preparation of composite membranes with tunable architecture and properties.