journal article·2024-01-17

Biotene: Earth-Abundant 2D Material as Sustainable Anode for Li/Na-Ion Battery

Atin Pramanik, Preeti Lata Mahapatra, Raphael Tromer, Jianan Xu, Gelu Costin, Chenxi Li, Sreehari Saju, Salma Alhashim, Kavita Pandey, Anchal Srivastava, Robert Vajtai, Douglas S. Galvao, Chandra Sekhar Tiwary, Pulickel M. Ajayan

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Abstract

Natural ores are abundant, cost-effective, and environmentally friendly. Ultrathin (2D) layers of a naturally abundant van der Waals mineral, Biotite, have been prepared in bulk via exfoliation. We report here that this 2D Biotene material has shown extraordinary Li–Na-ion battery anode properties with ultralong cycling stability. Biotene shows 302 and 141 mAh g –1 first cycle-specific charge capacity for Li- and Na-ion battery applications with ∼90% initial Coulombic efficiency. The electrode exhibits significantly extended cycling stability with ∼75% capacity retention after 4000 cycles even at higher current densities (500–2000 mA g –1 ). Further, density functional theory studies show the possible Li intercalation mechanism between the 2D Biotene layers. Our work brings new directions toward designing the next generation of metal-ion battery anodes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Material Science and NanoEngineering, Rice University, Houston, Texas 77005, United States

School of Nano Science and Technology, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India

Applied Physics Department, State University of Campinas, Campinas, SP 13083-970, Brazil

Department of Earth Environmental and Planetary Sciences, Rice University, Houston, Texas 77005, United States

Centre for Nano and Soft Matter Sciences (CeNS), Shivanapura, Bengaluru 562162, India

Department of Physics, Institute of Science, Banaras Hindu University, Varanasi 221005, India

Metallurgical and Materials Engineering, Indian Institute of Technology Kharagpur, Kharagpur 721302, India

Funding

Department of Atomic Energy, Government of India · Science and Engineering Research Board · Ministry of Education, India · Asian Office of Aerospace Research and Development · Omega Power

References (50)

Show source-provided references
1. 10.1021/cm901452z10.1021/cm901452z ↗
2. 10.1038/s41560-022-01073-y10.1038/s41560-022-01073-y ↗
3. 10.1021/acs.chemrev.0c0076710.1021/acs.chemrev.0c00767 ↗
4. 10.1021/acsami.9b1218710.1021/acsami.9b12187 ↗
5. 10.1039/c2cs35310e10.1039/c2cs35310e ↗
6. 10.1016/j.mattod.2020.11.02310.1016/j.mattod.2020.11.023 ↗
7. 10.1016/j.ensm.2021.11.05110.1016/j.ensm.2021.11.051 ↗
8. 10.1016/j.mattod.2022.07.00710.1016/j.mattod.2022.07.007 ↗
9. 10.1016/j.electacta.2019.04.01910.1016/j.electacta.2019.04.019 ↗
10. 10.1039/C9NR07849E10.1039/C9NR07849E ↗
11. 10.1039/D0TA08311A10.1039/D0TA08311A ↗
12. 10.1002/adma.20110499310.1002/adma.201104993 ↗
13. 10.1021/acsnano.5b0504010.1021/acsnano.5b05040 ↗
14. 10.1016/j.jpowsour.2020.22931810.1016/j.jpowsour.2020.229318 ↗
15. 10.1021/jp507336x10.1021/jp507336x ↗
16. 10.1021/jp410969u10.1021/jp410969u ↗
17. 10.1021/nn406156b10.1021/nn406156b ↗
18. 10.1016/j.nanoen.2016.03.01310.1016/j.nanoen.2016.03.013 ↗
19. 10.1038/nnano.2015.19410.1038/nnano.2015.194 ↗
20. 10.1021/nl504336h10.1021/nl504336h ↗
21. 10.1002/smll.20220166710.1002/smll.202201667 ↗
22. 10.1103/PhysRevMaterials.5.10400210.1103/PhysRevMaterials.5.104002 ↗
23. 10.1088/0953-8984/14/11/30210.1088/0953-8984/14/11/302 ↗
24. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗
25. 10.1103/PhysRevB.54.1116910.1103/PhysRevB.54.11169 ↗
26. 10.1103/PhysRevLett.103.09610210.1103/PhysRevLett.103.096102 ↗
27. 10.1016/j.commatsci.2014.11.02610.1016/j.commatsci.2014.11.026 ↗
28. 10.1103/PhysRevB.83.16511910.1103/PhysRevB.83.165119 ↗
29. 10.1103/PhysRevLett.74.396710.1103/PhysRevLett.74.3967 ↗
30. 10.1039/D0CP02869J10.1039/D0CP02869J ↗
31. 10.1016/j.cplett.2022.13992510.1016/j.cplett.2022.139925 ↗
32. 10.2138/am-2002-102410.2138/am-2002-1024 ↗
33. 10.1002/adma.20130187010.1002/adma.201301870 ↗
34. 10.1021/nl300090810.1021/nl3000908 ↗
35. 10.1186/s11671-021-03594-z10.1186/s11671-021-03594-z ↗
36. 10.1007/s11581-020-03574-w10.1007/s11581-020-03574-w ↗
37. 10.1039/c5nr05116a10.1039/c5nr05116a ↗
38. 10.1016/j.electacta.2016.04.16110.1016/j.electacta.2016.04.161 ↗
39. 10.1002/adma.20190828510.1002/adma.201908285 ↗
40. 10.1007/s11051-016-3401-610.1007/s11051-016-3401-6 ↗
41. 10.1002/smll.20190352210.1002/smll.201903522 ↗
42. 10.3390/batteries812026110.3390/batteries8120261 ↗
43. 10.1002/celc.20210019710.1002/celc.202100197 ↗
44. 10.1186/s11671-018-2699-710.1186/s11671-018-2699-7 ↗
45. 10.1149/1945-7111/acbba210.1149/1945-7111/acbba2 ↗
46. 10.1016/j.matchemphys.2021.12437310.1016/j.matchemphys.2021.124373 ↗
47. 10.1002/aenm.20230041310.1002/aenm.202300413 ↗
48. 10.1149/1945-7111/aba5d310.1149/1945-7111/aba5d3 ↗
49. 10.1021/acsaem.0c0181410.1021/acsaem.0c01814 ↗
50. 10.1016/j.mtadv.2020.10005410.1016/j.mtadv.2020.100054 ↗