journal article·2023-02-01Open access

Enhanced Thermoelectric Properties of a Semiconducting Two-Dimensional Metal–Organic Framework via Iodine Loading

Maria de Lourdes Gonzalez-Juarez, Mark A. Isaacs, Darren Bradshaw, Iris Nandhakumar

Abstract

High Resolution Image Download MS PowerPoint Slide We report the first result of a study in which molecular iodine has been incorporated via incipient wetness impregnation into the two-dimensional semiconducting metal–organic framework (MOF) Cu 3 (2,3,6,7,10,11-hexahydroxytriphenylene) 2 Cu 3 (HHTP) 2 to enhance its thermoelectric properties. A power factor of 0.757 μW m –1 K –2 for this MOF was obtained which demonstrates that this provides an effective route for the preparation of moderate-performance thermoelectric MOFs.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Metal-Organic Frameworks: Synthesis and Applications · Machine Learning in Materials Science

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Affiliations

School of Chemistry, University of Southampton, SouthamptonSO17 1BJ, U.K.

Department of Chemistry, University College London, LondonWC1H 0AJ, U.K.

HarwellXPS, Research Complex at Harwell, RAL, Harwell Campus, DidcotOX11 0FA, U.K.

Funding

Engineering and Physical Sciences Research Council · Consejo Nacional de Ciencia y Tecnolog?a

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