Thin Nano Cages with Limited Hollow Space for Ultrahigh Sulfur Loading Lithium–Sulfur Batteries

Owning to its various advantages, the lithium–sulfur battery is one of the research hot spots for new energy storage systems. Diverse hollow structures with specific morphologies have been used as the sulfur host materials to adsorb or/and catalyze the polysulfides, and can in particular concurrently inhibit the volume expansion during electrochemical processes in lithium–sulfur batteries. However, hollow space with a large volume will restrict the performance of the cell under high sulfur area loading, which is a very important indicator for the practical applications of the lithium–sulfur battery. Here, we report a nano thin cage cobalt acid zinc (ZnCo2O4) with limited hollow space as the cathode catalyst for lithium–sulfur batteries, which greatly reduces the electrode volume occupied by the hollow structure. The hollow volume of these thin cages is much smaller than those of the normally reported hollow materials in the literatue. The electrochemical performance of lithium–sulfur batteries with ZnCo2O4 thin cages could greatly improve due to the unique structure and the synergistic adsorption/catalytic effect of Zn/Co sites, especially at an ultrahigh S area load. Under a high S loading of 8 mg cm–2, the cell could keep a reversible capacity of 600 mAh g–1 after 500 cycles. Even at a sulfur loading of 10 mg cm–2, the cell still releases a discharge capacity of 1000 mAh g–1 which is equivalent of an area capacity of 10 mAh cm–2. This work provides a feasible way to develop lithium sulfur batteries with a high area sulfur load. This idea provides a possible solution to develop a Li–S battery at high area S loading and move one step closer to the practical applications.