journal article·2023-06-28

Tailoring Metal–Organic Frameworks and Derived Materials for High-Performance Zinc–Air and Alkaline Batteries

Atefeh Ashoori, Abolhassan Noori, Mohammad S. Rahmanifar, Ali Morsali, Nasim Hassani, Mehdi Neek-Amal, Hosein Ghasempour, Xinhui Xia, Yongqi Zhang, Maher F. El-Kady, Richard B. Kaner, Mir F. Mousavi

ACS Applied Materials & Interfaces· Volume 15· Issue 25
Publisher page

Abstract

Developing multifunctional materials from earth-abundant elements is urgently needed to satisfy the demand for sustainable energy. Herein, we demonstrate a facile approach for the preparation of a metal–organic framework (MOF)-derived Fe 2 O 3 /C, composited with N-doped reduced graphene oxide (MO-rGO). MO-rGO exhibits excellent bifunctional electrocatalytic activities toward the oxygen evolution reaction (η j=10 = 273 mV) and the oxygen reduction reaction (half-wave potential = 0.77 V vs reversible hydrogen electrode) with a low Δ E OER–ORR of 0.88 V in alkaline solutions. A Zn–air battery based on the MO-rGO cathode displays a high specific energy of over 903 W h kg Zn –1 (∼290 mW h cm –2 ), an excellent power density of 148 mW cm –2, and an open-circuit voltage of 1.430 V, outperforming the benchmark Pt/C + RuO 2 catalyst. We also hydrothermally synthesized a Ni-MOF that was partially transformed into a Ni–Co-layered double hydroxide (MOF-LDH). A MO-rGO||MOF-LDH alkaline battery exhibits a specific energy of 42.6 W h kg total mass –1 (106.5 μW h cm –2 ) and an outstanding specific power of 9.8 kW kg total mass –1 (24.5 mW cm –2 ). This work demonstrates the potential of MOFs and MOF-derived compounds for designing innovative multifunctional materials for catalysis, electrochemical energy storage, and beyond.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced battery technologies research · Electrocatalysts for Energy Conversion · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Faculty of Basic Sciences, Tarbiat Modares University, Tehran 14117-13116, Iran

Faculty of Basic Sciences, Shahed University, Tehran 3319118-651, Iran

Department of Physics, Shahid Rajaee Teacher Training University, Lavizan, Tehran, P.O. Box: 16875-163, Iran

Department of Physics, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium

College of Materials Science & Engineering, Zhejiang University of Technology, Hangzhou 310014, China

State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, School of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China

Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu 611371, China

Department of Chemistry and Biochemistry and California NanoSystems Institute, University of California, Los Angeles (UCLA), Los Angeles, California 90095, United States

Department of Materials Science and Engineering, University of California, Los Angeles (UCLA), Los Angeles, California 90095, United States

Funding

University of California, Los Angeles · California NanoSystems Institute · Tarbiat Modares University

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