Self-Standing, Photothermal-Actuating, and Motion-Monitoring Janus Films One-Pot Synthesized by Green Carboxymethyl Glucomannan/Liquid Metal Nanoinks

Downsizing bulk liquid metals (LM) at the nanometer scale with biocompatibility and multifunction is a key process for electronic or medical applications. Here, we report a stable and green LM aqueous colloidal ink by wrapping eutectic gallium-indium alloys (EGaIn) with carboxymethyl glucomannan (CGM) derived from radiata pine chip, which is capable of being prepared into a free-standing, photothermal-actuating, and motion-monitoring Janus film. With the assistance of CGM, the bulk EGaIn was ultrasonicated into stable nanodroplets (∼500 nm) with a typical "core-shell" structure, in which the colloidal inks can be stored for more than 1 week under room temperature. The stable CGM/EGaIn inks can be patterned on different substrates to form coating layers or self-assembled into free-standing Janus films with high mechanical strength and modulus (∼94 MPa and ∼3.8 GPa) by density deposition. Such a Janus film with anisotropic thermal conductivity made it a potential photothermal actuator. In addition, the biocompatible film demonstrated both high conductivity and large resistance variation in response to strain change (gauge factor >500), allowing for human motion monitoring. This work provides a new prospect for the development of biocompatible and high-performance nano-LM materials.