journal article·2021-11-24Open access

Evidence of Mn-Ion Structural Displacements Correlated with Oxygen Vacancies in La0.7Sr0.3MnO3 Interfacial Dead Layers

Piu Rajak, Daniel Knez, Sandeep Kumar Chaluvadi, Pasquale Orgiani, Giorgio Rossi, Laurence Méchin, Regina Ciancio

ACS Applied Materials & Interfaces· Volume 13· Issue 46

Abstract

(LSMO) thin films, compatible with the formation of well-known dead layers in manganites, with an elongated out-of-plane lattice parameter and structural and electronic properties well distinguished from the bulk of the film. We observed, for the first time, a structural shift of Mn ions coupled with oxygen vacancies and a reduced Mn valence state within such layer. Understanding the correlation between oxygen vacancies, the Mn oxidation state, and Mn-ion displacements is a prerequisite to engineer the magnetotransport properties of LSMO thin films.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Istituto Officina dei Materiali-CNR, Area Science Park, S.S.14, km 163.5, 34149 Trieste, Italy

Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz, Austria

CNR-SPIN, UOS Salerno, 84084 Fisciano, Salerno, Italy

Dipartimento di Fisica, Università degli Studi di Milano, Via Celoria 16, 20133 Milano, Italy

Normandie University, UNICAEN, ENSICAEN, CNRS, GREYC, 14000 Caen, France

Funding

Abdus Salam International Centre for Theoretical Physics · Horizon 2020 Framework Programme · H2020 Excellent Science · Zukunftsfonds Steiermark

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