DataVXACS Applied Materials & InterfacesPaper
journal article·2022-11-16

Visible Light-Driven Metal–Organic Framework-Mediated Activation and Utilization of CO2 for the Thiocarboxylation of Olefins

Sandhya Saini, Debabrata Chakraborty, E. S. Erakulan, Ranjit Thapa, Rajaram Bal, Asim Bhaumik, Suman L. Jain

ACS Applied Materials & Interfaces· Volume 14· Issue 45
Publisher page
Source abstract

Abstract

Visible light-mediated photoredox catalysis has emerged to be a fascinating approach for the activation of CO 2 and its subsequent fixation into valuable chemicals utilizing renewable and inexhaustible solar energy. Although great progress has been made in CO 2 photoreduction, visible light-assisted organic synthesis using CO 2 as a reactive substrate is rarely explored. Herein, we report an efficient, facile, and economically viable photoredox-mediated approach for the synthesis of important β-thioacids via carboxylation of olefins with CO 2 and thiols over a porous functionalized metal–organic framework (MOF), Fe-MIL-101-NH 2, as a photocatalyst under ambient conditions. This multicomponent reaction offers wide substrate scope, mild reaction conditions, easy work-up, cost-effective and reusable photocatalysts, and higher product selectivity. Computational studies suggested that CO 2 interacts with the thiophenol–styrene adduct to facilitate the synthesis of β-thioacids in almost quantitative yields.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Carbon dioxide utilization in catalysis · Metal-Organic Frameworks: Synthesis and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chemical & Material Sciences Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun 248005, India

Academy of Scientific and Innovative Research, Ghaziabad, Uttar Pradesh 201 002, India

School of Materials Sciences, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata 700 032, India

Department of Physics, SRM University-AP, Amaravati 522240, Andhra Pradesh, India

Light Stock Process Division, CSIR-Indian Institute of Petroleum, Haridwar Road, Mohkampur, Dehradun 248005, India

Funding

Council of Scientific and Industrial Research · Department of Science and Technology, Ministry of Science and Technology · Indo-German Science and Technology Centre

References (48)

Show source-provided references
1. 10.1039/B912904A10.1039/B912904A ↗
2. 10.1021/jacs.5b1333510.1021/jacs.5b13335 ↗
3. 10.1016/j.jcis.2016.05.03710.1016/j.jcis.2016.05.037 ↗
4. 10.1021/acsami.0c1826710.1021/acsami.0c18267 ↗
5. 10.1021/jacs.1c0857810.1021/jacs.1c08578 ↗
6. 10.1021/acsami.1c0994210.1021/acsami.1c09942 ↗
7. 10.1002/anie.20200863010.1002/anie.202008630 ↗
8. 10.1038/s41929-022-00841-z10.1038/s41929-022-00841-z ↗
9. 10.1039/D2CC03380A10.1039/D2CC03380A ↗
10. 10.1016/j.chempr.2020.08.02210.1016/j.chempr.2020.08.022 ↗
11. 10.1002/anie.20200863010.1002/anie.202008630 ↗
12. 10.1002/cssc.20200197410.1002/cssc.202001974 ↗
13. 10.1021/jacs.0c0314410.1021/jacs.0c03144 ↗
14. 10.1038/s41467-020-17085-910.1038/s41467-020-17085-9 ↗
15. 10.1002/cssc.20210196310.1002/cssc.202101963 ↗
16. 10.1080/01614940.2020.183175710.1080/01614940.2020.1831757 ↗
17. 10.1246/bcsj.39.91710.1246/bcsj.39.917 ↗
18. 10.1016/j.tetlet.2019.06.06110.1016/j.tetlet.2019.06.061 ↗
19. 10.1039/C4RA04897K10.1039/C4RA04897K ↗
20. 10.1002/anie.20170786210.1002/anie.201707862 ↗
21. 10.1039/C8CS00829A10.1039/C8CS00829A ↗
22. 10.1021/acsami.1c0371710.1021/acsami.1c03717 ↗
23. 10.1002/chem.20130172810.1002/chem.201301728 ↗
24. 10.1039/C4SC03224A10.1039/C4SC03224A ↗
25. 10.1021/jacs.8b1371010.1021/jacs.8b13710 ↗
26. 10.1016/j.apmt.2020.10091510.1016/j.apmt.2020.100915 ↗
27. 10.1021/ic800538r10.1021/ic800538r ↗
28. 10.1016/j.micromeso.2012.06.04410.1016/j.micromeso.2012.06.044 ↗
29. 10.1021/ja312120x10.1021/ja312120x ↗
30. 10.1016/j.inoche.2018.05.00710.1016/j.inoche.2018.05.007 ↗
31. 10.1021/cm051870o10.1021/cm051870o ↗
32. 10.1039/C2CE26586A10.1039/C2CE26586A ↗
33. 10.1021/ja067544710.1021/ja0675447 ↗
34. 10.1021/ic401784910.1021/ic4017849 ↗
35. 10.3390/molecules2304075510.3390/molecules23040755 ↗
36. 10.1039/C6CC02011A10.1039/C6CC02011A ↗
37. 10.1021/acscatal.9b0547010.1021/acscatal.9b05470 ↗
38. 10.1039/c2dt30672g10.1039/c2dt30672g ↗
39. 10.1039/D1NJ03468E10.1039/D1NJ03468E ↗
40. 10.1039/C4RA06522K10.1039/C4RA06522K ↗
41. 10.1021/cs501169t10.1021/cs501169t ↗
42. 10.1002/cctc.20190194410.1002/cctc.201901944 ↗
43. 10.1007/s13738-019-01647-w10.1007/s13738-019-01647-w ↗
44. 10.1016/j.poly.2016.10.03210.1016/j.poly.2016.10.032 ↗
45. 10.1021/acs.accounts.1c0013510.1021/acs.accounts.1c00135 ↗
46. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
47. 10.1103/PhysRevB.50.1795310.1103/PhysRevB.50.17953 ↗
48. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗