Bioinspired Multiple Stimuli-Responsive Optical Microcapsules Enabled by Microfluidics

Optical microcapsules encapsulating optical materials inside a symmetric spherical confinement are significant elements for the construction of optical units and the integration of optical arrays. However, the multiple stimuli-responsive characteristic of optical microcapsules still remains a challenge due to the insuperable physical barrier between the optical material core and the outside shell and the lack of effective mechanisms to trigger the dynamic switch of the encapsulated optical materials. Inspired by the dual-mode optical modulation of chameleon skins, a novel biomimetic binary optical microcapsule that combines the visible light reflection of chiral nematic liquid crystals and photoluminescence emission of rare-earth complexes is assembled by microfluidic emulsification and interfacial polymerization. The reflected color, fluorescent intensity, and size of the optical microcapsules are facilely controlled in the microfluidic chip by adjusting the composition and flow rate of the injected fluids. Most importantly, the biomimetic binary optical microcapsules demonstrate three reversible responsive behaviors, thermotropic reflection evolution, temperature-dependent fluorescence emission, and Fredericks electro-optical response. The bioinspired multiple stimuli-responsive optical microcapsules enabled by microfluidics provide a templated strategy to manufacture the next generation of intelligent optical units and to achieve the dynamic response of hybrid photonic devices.