journal article·2022-08-03

Black Phosphorus: Fundamental Properties and Influence of Impurities Induced by Its Synthesis

Nikolas Antonatos, Jiří Šturala, Vlastimil Mazánek, David Sedmidubský, Martin Veselý, Květoslav Růžička, Jiři Hejtmánek, Petr Levinsky, Zdeněk Sofer

ACS Applied Materials & Interfaces· Volume 14· Issue 30
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Abstract

Black phosphorus (BP) has been among the most widely explored materials in recent years because of its exceptional properties. A vapor transport method using tin and iodide as mineralizers was used to synthesize large crystals which can be used for fundamental physical characterization including electrical and heat transport and heat capacity. This method is compared to other reported procedures (high-pressure crystal growth and mercury catalysis) which are broadly used and the most dominant procedures for the obtainment of bulk layered BP. In addition, we have investigated any possible impurities which could have been introduced by synthesis and their possible incorporation into BP and their influence on the physical properties of BP.
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Research context

OpenAlex topics: 2D Materials and Applications · MXene and MAX Phase Materials · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic

Department of Organic Technology, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic

Department of Physical Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic

Institute of Physics of the Czech Academy of Sciences, v.v.i., Cukrovarnická 112/10, 162 00 Prague, Czech Republic

Funding

Grantová Agentura Ceské Republiky · Vysoká Å kola Chemicko-technologická v Praze

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