Soft–Hard Segment Combined Carbonized Polymer Dots for Flexible Optical Film with Superhigh Surface Hardness

The rapid development of optical and electronic devices has driven up the demand of high performance optical protective films to avoid exterior influence and extend the service life. But it is not easy to obtain an ideal coating film with high transmittance, high hardness, and good flexibility. Herein, by taking advantage of the special core-shell structure of carbonized polymer dots (CPDs), we propose a strategy to build up a nanoscale soft-hard segment microstructure for optical protective coating materials. The CPDs with hard core and soft polymer chain shell are prepared from citric acid and (3-aminopropyl)triethoxysilane. The as-prepared CPDs can be converted directly to the coating film by the dehydration and cross-linking. In addition to the good optical transmittance, the final film exhibits simultaneously ultrahigh 9H pencil hardness to stand 4000 cycles of a steel-wool wear test, and excellent flexibility to stand bending and rolling-up.