journal article·2019-09-25

Controlled Spacing between Nanopatterned Regions in Block Copolymer Films Obtained by Utilizing Substrate Topography for Local Film Thickness Differentiation

Elisheva Michman, Marcel Langenberg, Roland Stenger, Meirav Oded, Mark Schvartzman, Marcus Müller, Roy Shenhar

ACS Applied Materials & Interfaces· Volume 11· Issue 38
Publisher page

Abstract

Various types of devices require hierarchically nanopatterned substrates, where the spacing between patterned domains is controlled. Ultraconfined films exhibit extreme morphological sensitivity to slight variations in film thickness when the substrate is highly selective toward one of the blocks. Here, it is shown that using the substrate's topography as a thickness differentiating tool enables the creation of domains with different surface patterns in a fully controlled fashion from a single, unblended block copolymer. This approach is applicable to block copolymers of different compositions and to different topographical patterns and thus opens numerous possibilities for the hierarchical construction of multifunctional devices.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Block Copolymer Self-Assembly · Fluid Dynamics and Thin Films · Theoretical and Computational Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The Institute of Chemistry and the Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 9190401, Israel

Institute for Theoretical Physics, Georg-August-University Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany

Department of Materials Engineering and Ilse Katz Institute for Nanoscale Science and Technology, Ben Gurion University of the Negev, Beer Sheva 8410501, Israel

Funding

Israel Science Foundation · Deutsche Forschungsgemeinschaft · CAMBR Charitable Foundation

References (74)

Show source-provided references
1. 10.1002/lpor.20140040210.1002/lpor.201400402 ↗
2. 10.1088/0034-4885/79/7/07640110.1088/0034-4885/79/7/076401 ↗
3. 10.1021/nn505630t10.1021/nn505630t ↗
4. 10.1126/science.111484910.1126/science.1114849 ↗
5. 10.1089/ten.2006.015410.1089/ten.2006.0154 ↗
6. 10.1021/nl104378f10.1021/nl104378f ↗
7. 10.1039/C8NR04038A10.1039/C8NR04038A ↗
8. 10.1002/adma.20120233110.1002/adma.201202331 ↗
9. 10.1021/acs.nanolett.6b0061810.1021/acs.nanolett.6b00618 ↗
10. 10.1364/OE.15.00447410.1364/OE.15.004474 ↗
11. 10.1103/PhysRevLett.82.260210.1103/PhysRevLett.82.2602 ↗
12. 10.1038/nature0177510.1038/nature01775 ↗
13. 10.1038/nmat121110.1038/nmat1211 ↗
14. 10.1126/science.115762610.1126/science.1157626 ↗
15. 10.1021/nl035005j10.1021/nl035005j ↗
16. 10.1002/1521-4095(200108)13:15<1152::AID-ADMA1152>3.0.CO;2-510.1002/1521-4095(200108)13:15<1152::AID-ADMA1152>3.0.CO;2-5 ↗
17. 10.1021/am302830w10.1021/am302830w ↗
18. 10.1002/adma.20100166910.1002/adma.201001669 ↗
19. 10.1038/ncomms1051810.1038/ncomms10518 ↗
20. 10.1038/ncomms844810.1038/ncomms8448 ↗
21. 10.1126/science.121843710.1126/science.1218437 ↗
22. 10.1021/acsami.9b0363210.1021/acsami.9b03632 ↗
23. 10.1038/ncomms1398810.1038/ncomms13988 ↗
24. 10.1021/acs.langmuir.6b0136510.1021/acs.langmuir.6b01365 ↗
25. 10.1021/acsnano.7b0032210.1021/acsnano.7b00322 ↗
26. 10.1021/acsnano.8b0285110.1021/acsnano.8b02851 ↗
27. 10.1021/nn700341s10.1021/nn700341s ↗
28. 10.1126/science.111104110.1126/science.1111041 ↗
29. 10.1021/nn700164p10.1021/nn700164p ↗
30. 10.1002/adfm.20090222910.1002/adfm.200902229 ↗
31. 10.1038/nnano.2010.3010.1038/nnano.2010.30 ↗
32. 10.1038/ncomms430510.1038/ncomms4305 ↗
33. 10.1002/smll.20130106610.1002/smll.201301066 ↗
34. 10.1557/jmr.2010.7410.1557/jmr.2010.74 ↗
35. 10.1186/s40580-018-0156-z10.1186/s40580-018-0156-z ↗
36. 10.1002/marc.20170028510.1002/marc.201700285 ↗
37. 10.1038/ncomms1236610.1038/ncomms12366 ↗
38. 10.1021/nl203445h10.1021/nl203445h ↗
39. 10.1021/acsmacrolett.8b0011910.1021/acsmacrolett.8b00119 ↗
40. 10.1021/nn101212q10.1021/nn101212q ↗
41. 10.1039/C9CP02667C10.1039/C9CP02667C ↗
42. 10.1039/C9CP00949C10.1039/C9CP00949C ↗
43. 10.1126/science.115935210.1126/science.1159352 ↗
44. 10.1063/1.151935610.1063/1.1519356 ↗
45. 10.1021/acsami.7b1771310.1021/acsami.7b17713 ↗
46. 10.1088/0957-4484/25/39/39530110.1088/0957-4484/25/39/395301 ↗
47. 10.1021/nl049209r10.1021/nl049209r ↗
48. 10.1038/ncomms680510.1038/ncomms6805 ↗
49. 10.1021/nn305126410.1021/nn3051264 ↗
50. 10.1021/ma500716f10.1021/ma500716f ↗
51. 10.1002/marc.20070048610.1002/marc.200700486 ↗
52. 10.1088/0957-4484/21/49/49530110.1088/0957-4484/21/49/495301 ↗
53. 10.1021/acsami.7b0050910.1021/acsami.7b00509 ↗
54. 10.1021/ma402416g10.1021/ma402416g ↗
55. 10.1209/epl/i1997-00517-610.1209/epl/i1997-00517-6 ↗
56. 10.1146/annurev.matsci.31.1.32310.1146/annurev.matsci.31.1.323 ↗
57. 10.1021/jp309546q10.1021/jp309546q ↗
58. 10.1103/PhysRevLett.89.03550110.1103/PhysRevLett.89.035501 ↗
59. 10.1063/1.162732510.1063/1.1627325 ↗
60. 10.1021/ma049776110.1021/ma0497761 ↗
61. 10.1021/ma202616w10.1021/ma202616w ↗
62. 10.1021/acs.macromol.7b0118510.1021/acs.macromol.7b01185 ↗
63. 10.1021/ma970977x10.1021/ma970977x ↗
64. 10.1007/s10189017014410.1007/s101890170144 ↗
65. 10.1021/am300201a10.1021/am300201a ↗
66. 10.1016/0378-4371(92)90294-Z10.1016/0378-4371(92)90294-Z ↗
67. 10.1103/PhysRevE.86.01080110.1103/PhysRevE.86.010801 ↗
68. 10.1038/nature0331010.1038/nature03310 ↗
69. 10.1002/adfm.20130009110.1002/adfm.201300091 ↗
70. 10.1021/ac00100a00810.1021/ac00100a008 ↗
71. 10.1016/j.colsurfb.2006.08.00510.1016/j.colsurfb.2006.08.005 ↗
72. 10.1007/s10955-011-0302-z10.1007/s10955-011-0302-z ↗
73. 10.1063/1.236450610.1063/1.2364506 ↗
74. 10.1063/1.299734510.1063/1.2997345 ↗