journal article·2023-09-13Open access

Novel Biocompatible Trianglamine Networks for Efficient Iodine Capture

Belkacem Tarek Benkhaled, Arnaud Chaix, Chaimaa Gomri, Sébastien Buys, Nabil Namar, Nadine Sehoulia, Rohitkumar Jadhav, Jason Richard, Laure Lichon, Christophe Nguyen, Magali Gary-Bobo, Mona Semsarilar

ACS Applied Materials & Interfaces· Volume 15· Issue 36

Abstract

Herein, we report for the first time a biocompatible cross-linked trianglamine (Δ) network for the efficient iodine removal from the vapor phase, water, and seawater. In the vapor phase, the cross-linked network could capture 6 g g –1 of iodine, ranking among the most performant materials for iodine vapor capture. In the liquid phase, this cross-linked network is also capable of capturing iodine at high rates from aqueous media (water and seawater). This network displayed fast adsorption kinetics, and they are fully recyclable. This study reveals the high affinity of iodine for the intrinsic cavity of the trianglamine. The synthesized materials are extremely interesting since they are environmentally friendly and inexpensive and the synthesis could easily be scaled up to be used as the material of choice in response to accidents in the nuclear industry.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supramolecular Chemistry and Complexes · Luminescence and Fluorescent Materials · Molecular Sensors and Ion Detection

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

IEM, Univ Montpellier, CNRS, ENSCM, Institut Européen des Membranes, Montpellier 34095, France

IBMM, Univ Montpellier, CNRS, ENSCM, Institut des Biomolécules Max Mousseron, Montpellier 34095, France

Funding

Agence Nationale de la Recherche · Universit? de Montpellier · H2020 European Research Council · Laboratoire d?Excellence sur la Chimie des Syst?mes Mol?culaires et Interfaciaux

References (57)

Show source-provided references
1. 10.1039/C8RA04775H10.1039/C8RA04775H ↗
2. 10.1016/j.jhazmat.2017.10.06510.1016/j.jhazmat.2017.10.065 ↗
3. 10.1021/acs.iecr.6b0418910.1021/acs.iecr.6b04189 ↗
4. 10.1002/aic.1543210.1002/aic.15432 ↗
5. 10.1007/BF0335369310.1007/BF03353693 ↗
6. 10.1002/admi.20190024910.1002/admi.201900249 ↗
7. 10.1039/C8MH01656A10.1039/C8MH01656A ↗
8. 10.1002/adfm.20180159610.1002/adfm.201801596 ↗
9. 10.1039/C9TA04408F10.1039/C9TA04408F ↗
10. 10.1021/acsami.0c0212910.1021/acsami.0c02129 ↗
11. 10.1021/ja204757x10.1021/ja204757x ↗
12. 10.1038/s41467-022-30663-310.1038/s41467-022-30663-3 ↗
13. 10.1021/jacs.7b0320410.1021/jacs.7b03204 ↗
14. 10.1002/anie.20210852210.1002/anie.202108522 ↗
15. 10.1002/adma.20180199110.1002/adma.201801991 ↗
16. 10.1021/jacs.2c0395910.1021/jacs.2c03959 ↗
17. 10.1021/acsmacrolett.7b0084910.1021/acsmacrolett.7b00849 ↗
18. 10.1021/acsanm.2c0056410.1021/acsanm.2c00564 ↗
19. 10.1021/acsami.2c0728810.1021/acsami.2c07288 ↗
20. 10.1021/acs.jpcc.2c0872310.1021/acs.jpcc.2c08723 ↗
21. 10.1002/chem.20210443710.1002/chem.202104437 ↗
22. 10.1021/acsami.1c2138010.1021/acsami.1c21380 ↗
23. 10.1016/j.jhazmat.2021.12589010.1016/j.jhazmat.2021.125890 ↗
24. 10.1021/acs.inorgchem.2c0188610.1021/acs.inorgchem.2c01886 ↗
25. 10.1021/acsapm.0c0113610.1021/acsapm.0c01136 ↗
26. 10.1039/C9TA05782J10.1039/C9TA05782J ↗
27. 10.1002/anie.20211372410.1002/anie.202113724 ↗
28. 10.1021/acs.chemrev.5b0034110.1021/acs.chemrev.5b00341 ↗
29. 10.1021/acsami.0c0967310.1021/acsami.0c09673 ↗
30. 10.1002/adma.20210740110.1002/adma.202107401 ↗
31. 10.1039/C8CS00271A10.1039/C8CS00271A ↗
32. 10.1039/C7CS00391A10.1039/C7CS00391A ↗
33. 10.1016/j.chempr.2021.01.00210.1016/j.chempr.2021.01.002 ↗
34. 10.1021/jacs.7b0985010.1021/jacs.7b09850 ↗
35. 10.1021/jacs.8b0877010.1021/jacs.8b08770 ↗
36. 10.1016/j.ccr.2019.21316510.1016/j.ccr.2019.213165 ↗
37. 10.1002/anie.20181397210.1002/anie.201813972 ↗
38. 10.1002/ange.20080571210.1002/ange.200805712 ↗
39. 10.1002/anie.20100014110.1002/anie.201000141 ↗
40. 10.1038/ncomms765010.1038/ncomms7650 ↗
41. 10.1039/C0SM01041C10.1039/C0SM01041C ↗
42. 10.1021/ja106362w10.1021/ja106362w ↗
43. 10.1039/C9NR09532B10.1039/C9NR09532B ↗
44. 10.1016/j.snb.2019.05.00810.1016/j.snb.2019.05.008 ↗
45. 10.1038/s41467-020-19404-610.1038/s41467-020-19404-6 ↗
46. 10.1039/D2CC03574J10.1039/D2CC03574J ↗
47. 10.1039/D2SC00207H10.1039/D2SC00207H ↗
48. 10.1039/D1CC03531B10.1039/D1CC03531B ↗
49. 10.1021/jacs.0c1301910.1021/jacs.0c13019 ↗
50. 10.1021/jo000623v10.1021/jo000623v ↗
51. 10.1002/chem.20050088710.1002/chem.200500887 ↗
52. 10.1016/j.ijhydene.2011.10.00910.1016/j.ijhydene.2011.10.009 ↗
53. 10.1016/j.apsusc.2015.05.18610.1016/j.apsusc.2015.05.186 ↗
54. 10.1038/s41467-022-34296-410.1038/s41467-022-34296-4 ↗
55. 10.1021/cr020410110.1021/cr0204101 ↗
56. 10.1039/C9CC08699D10.1039/C9CC08699D ↗
57. 10.1016/j.jhazmat.2020.12215610.1016/j.jhazmat.2020.122156 ↗