journal article·2023-01-25

Surface Site-Specific Replacement for Catalysis Selectivity Switching

Jun Zha, Xiangfu Meng, Wentao Fan, Qing You, Nan Xia, Wanmiao Gu, Yan Zhao, Lin Hu, Jin Li, Haiteng Deng, Hui Wang, Nan Yan, Zhikun Wu

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Abstract

Surface atom replacement in materials without other composition/structure changes is challenging but is important for fundamental scientific research and for practical applications. In particular, for nanoparticles including nanoclusters, surface metal site-specific replacement with atomic precision has not yet been achieved. In this study, we for the first time achieved surface site-specific antigalvanic replacement with the remaining composition/structure and surface replacement-dependent selectivity in the electrocatalytic reduction of CO 2 . Density functional theory (DFT) calculations describe the catalysis selectivity switch induced by replacing Ag with Cu and explain why Cu replacement facilitates C 2 production. Also, CO 2 electroreduction to C 2 on well-defined metal nanoclusters is first reported in this study.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: CO2 Reduction Techniques and Catalysts · Nanocluster Synthesis and Applications · Surface Chemistry and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, PR China

University of Science and Technology of China, Hefei 230026, PR China

Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, PR China

High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, PR China

Tsinghua University-Peking University Joint Center for Life Sciences, School of Life Sciences, Tsinghua University,Beijing 100084, PR China

MOE Key Laboratory of Bioinformatics, School of Life Sciences, Tsinghua University, Beijing 100084, PR China

Funding

State Administration of Foreign Experts Affairs · Hefei Center for Physical Science and Technology · China Postdoctoral Science Foundation · National Natural Science Foundation of China · Natural Science Foundation of Anhui Province · Chinese Academy of Sciences

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