Robust Scalable-Manufactured Smart Fabric Surfaces Based on Azobenzene-Containing Maleimide Copolymers for Rewritable Information Storage and Hydrogen Fluoride Visual Sensor

Functionalized materials with reversible color switching are highly attractive in many application fields, especially as rewritable media for information storage. It is critical yet challenging to develop a cost-effective strategy for the fabrication of stimulus-responsive chromogenic systems. Herein, we present a versatile dip-coating approach to fabricate robust smart textile with acid/base-driven chromotropic capability. Owing to the introduction of novel maleimide-based copolymers bearing azobenzene derivative moieties, smart textiles possess rapid color switching between yellow and orange-red, which is triggered by acid-base stimulations with the resulting reversible protonation/deprotonation of maleimide moieties. As a proof of concept of the application of the smart textile for high-performance rewritable media, various rewritable elaborate patterns can be fast trifluoroacetic acid-printed/triethylamine-erased (within 20 s) with excellent cycling stability and long legible duration (>30 days). Meanwhile, the smart textile can be employed as a visual sensor for the detection of hydrogen fluoride gas leakage. It is highlighted that the as-prepared robust smart textiles with superhydrophobic surfaces have excellent antifouling properties and chemical/mechanical stabilities, which can tolerate harsh environmental conditions and repetitive mechanical deformation. The robust smart textiles with simple low-cost large-scale production may find more advanced potential applications besides information storage and sensors demonstrated.