Multifunctional Behavior of Sulfonate-Based Hydrolytically Stable Microporous Metal–Organic Frameworks
Source abstract
Abstract
An isostructural pair of extremely rare, permanently microporous sulfonate-based metal–organic frameworks (MOFs) having a novel topology has been reported here by integration of rationally chosen building units. The compounds bear polar sites in the pore surfaces and exhibit selective adsorption of CO2, which features among the highest reported uptakes in the domain of organosulfonate-based MOFs. The compounds also exhibit multifunctionality for C6-cyclic hydrocarbon separation and selective detection of neurotransmitter nitric oxide. Such multifunctional behavior on the basis of permanent porosity has been rarely observed for sulfonate-based MOFs. The efficacy of the synthesis approach is further highlighted by the resistance over a wide pH range and promising feasibility of reticular chemistry in porous organosulfonate-based systems.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Arsenic contamination and mitigation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Indian Institute of Science Education and Research (IISER), Dr. Homi Bhabha Road, Pashan, Pune 411 008, India
School of Science, RMIT University, Melbourne, Melbourne 3001, Australia
Commonwealth Scientific and Industrial Research Organisation (CSIRO) Manufacturing, Clayton, Victoria 3169, Australia
Centre for Energy Science, IISER Pune, Pune 411 008, India
Funding
Council of Scientific and Industrial Research · University Grants Commission · Science and Engineering Research Board · Nano Mission Council, Department of Science and Technology · Australian Research Council · Department of Science and Technology, Ministry of Science and Technology · Indian Institute of Science Education and Research Pune
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