journal article·2023-04-05

Interfacial Engineering Boosts Highly Reversible Zinc Metal for Aqueous Zinc-Ion Batteries

Danwen Yao, Dongxu Yu, Shiyu Yao, Ziheng Lu, Guoxiao Li, Huailiang Xu, Fei Du

ACS Applied Materials & Interfaces· Volume 15· Issue 13
Publisher page

Abstract

Zinc metal is emerging as the promising anode for aqueous Zn-ion batteries. However, corrosion and undesirable Zn dendrite growth limit their practical application in the large-scale energy storage area. Herein, a mountain–valley micro/nanostructure is successfully fabricated on the surface of the Zn anode via a femtosecond-laser filament texturing (FsLFT) technique. Beneficial from the large surface area and spontaneously generated ZnO coating layer, the FsLFT-Zn electrode demonstrates a slow corrosion rate with a current density of 0.62 mA cm –2 and a stable cycle life over 3000 h under 1 mA cm –2, superior to the original Zn anode. Simulation of the electric fields reveals that the enlarged surface area is responsible for the outstanding performance of the FsLFT-Zn electrode. This study not only proposes a novel strategy to suppress dendrite growth toward highly stable AZIBs but also opens a new avenue to solve similar issues in other metal batteries.
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Research context

OpenAlex topics: Advanced battery technologies research · Perovskite Materials and Applications · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, People’s Republic of China

Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, People’s Republic of China

Institute of Zhejiang University─Quzhou, Quzhou 324000, People’s Republic of China

Microsoft Research, No. 5 Dan Ling Street, Haidian District, Beijing 100080, People’s Republic of China

Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, People’s Republic of China

State Key Laboratory of Precision Spectroscopy & Chongqing Institute, East China Normal University, Shanghai 200062, People’s Republic of China

CAS Center for Excellence in Ultra-Intense Laser Science, Shanghai 201800, People’s Republic of China

Funding

Central University Basic Research Fund of China · Jilin University · Department of Science and Technology of Jilin Province · National Natural Science Foundation of China

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