Processable Conjugated Microporous Polymer Gels and Monoliths: Fundamentals and Versatile Applications

Conjugated microporous polymers (CMPs) as a new type of conjugated polymers have attracted extensive attention in academia and industry because of the combination of microporous structure and π-electron conjugated structure. The construction and application of gels and monoliths based on CMPs constitute a fertile area of research, promising to provide solutions to complex environmental and energy issues. This review summarizes and objectively analyzes the latest advances in the construction and application of processable CMP gels and monoliths, linking the basic and enhanced properties to widespread applications. In this review, we open with a summary of the construction methods used to build CMP gels and monoliths and assess the feasibility of different preparation techniques and the advantages of the products. The CMP gels and monoliths with enhanced properties involving various special applications are then deliberated by highlighting relevant scientific literature and discussions. Finally, we present the issues and future of openness in the field, as well as come up with the major challenges hindering further development, to guide researchers in this field.