In Situ Spectroelectrochemical Detection of Oxygen Evolution Reaction Intermediates with a Carboxylated Graphene–MnO₂ Electrocatalyst

In electrocatalyst-assisted water splitting, the oxygen evolution reaction (OER) imposes a performance limit due to the formation of different catalyst-bound intermediates and the scaling relationship of their adsorption energies. To break this scaling relationship in OER, a bifunctional mechanism was proposed recently, in which the energetically demanding step of forming the *OOH intermediate, through the attack of a water molecule on the oxo unit (*O, with * representing a reactive metal center), is facilitated by proton transfer to the second catalytic site. This mechanism was supported theoretically but so far by only very few experiments with a proton-transfer agent in basic media. However, active metal-containing catalysts could be destroyed in alkaline media, raising questions on practical applications. To date, this mechanism still lacks a systematic spectroscopic support by observing the short-lived and limited amount of reactive intermediates. Here, we report an operando Raman spectroscopic observation of the OER intermediates in neutral media, for the first time, via a bifunctional mechanism using a carboxylated graphene–MnO2 (represented by Gr-C-MnO2) electrocatalyst. The formation of the Mn–OOH intermediate after the attack of a water molecule on the Mn═O complex is followed by a proton transfer from Mn–OOH to the functionalized carboxylates. The role of the functionalized carboxylates to improve the catalytic efficiency was further confirmed by both pH-dependent and isotope (H/D)-labeling experiments. Furthermore, with a unique strategy of using a hybrid aqueous/nonaqueous electrolyte, the OER was alleviated, allowing sufficient Mn–OH and Mn–OOH intermediates for in situ Raman spectroscopic observation.