Photocontrolled Coumarin-diphenylalanine/Cyclodextrin Cross-Linking of 1D Nanofibers to 2D Thin Films

Using coumarin-modified diphenylalanine (CO-FF) and γ-cyclodextrin (γ-CD) as building blocks, we successfully constructed one-dimensional nanofibers with several nanometers in width and tens of micrometers in length. Through the photodimerization of coumarin units in CO-FF⊂γ-CD complexes, the resultant nanofibers could be cross-linked to organic 2D thin films with a lateral dimension of tens of micrometers and a thickness of nanometers. The resultant thin films exhibited a significant fluorescence enhancement for twisted intramolecular charge-transfer (TICT) molecules and effective removal of pollutant from water through filtration. This 1D → 2D morphological conversion controlled by light may provide a novel strategy to construct the highly ordered nanostructures that can be used as templates for making nanoscaled materials with defined sizes and shapes.