Laminated MXene Foam/Cellulose@LDH Composite Membrane with Efficient EMI Shielding Property for Asymmetric Personal Thermal Management

Facing the increasingly complex and deteriorated environment, people's thermal comfort and health requirements are expanding. Therefore, wearable materials with integrated functions have progressed rapidly due to the fair compatibility for various functions and precise regulation. In this work, a laminated MXene foam/cellulose@LDH composite membrane was fabricated via a facile process consisting of in situ growth, vacuum filtration, and foaming for asymmetrical personal thermal management and electromagnetic interference shielding. In detail, the Zn-Al LDH side shows a high solar reflectance of 0.89 and an infrared emissivity of 0.97 in the atmospheric window, demonstrating the superior radiative cooling property. In contrast, the outstanding radiative warming performance is revealed by the high solar absorption (0.72) and infrared reflectivity (0.55) of the MXene foam. As a result, prominent temperature differences were achieved during the validation test. Compared to the control group, an 18 °C reduction of the Zn-Al LDH side and a 9.6 °C increment of the MXene foam side were observed, bringing out the excellent optical properties and radiative thermal management performances. What is more, due to the outstanding electrical conductivity of MXene, a rapid and prominent temperature rise to 44.2 °C could be expected by applying a low voltage of 1 V to provide active joule warmth. In addition, hydrophobization and the associated stain resistance were explained by the high water contact angles of obtained membranes. The excellent electromagnetic interference shielding performance (43.9 dB) given by the introduction of MXene provides a prospective candidate to replace the common shielding materials. The results, in general, provide a promising strategy for meeting the updating requirements for comfortable living in a world full of potential thermal and health threats.