DataVXACS Applied Materials & InterfacesPaper
journal article·2022-01-26Open access

Zirconium-Based Metal–Organic Framework Mixed-Matrix Membranes as Analytical Devices for the Trace Analysis of Complex Cosmetic Samples in the Assessment of Their Personal Care Product Content

Adrián Gutiérrez-Serpa, Tanay Kundu, Jorge Pasán, Ana I. Jiménez-Abizanda, Stefan Kaskel, Irena Senkovska, Verónica Pino

ACS Applied Materials & Interfaces· Volume 14· Issue 3
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Abstract

A device comprising a zirconium-based metal–organic framework (MOF) mixed-matrix membrane (MMM) framed in a plastic holder has been used to monitor the content of personal care products (PCPs) in cosmetic samples. Seven different devices containing the porous frameworks UiO-66, UiO-66-COOH, UiO-67, DUT-52, DUT-67, MOF-801, and MOF-808 in polyvinylidene fluoride (PVDF) membranes were studied. Optimized membranes reach high adsorption capacities of PCPs, up to 12.5 mg·g–1 benzophenone in a 3.0 mg·L–1 sample. The MMM adsorption kinetics, uptake measurements, and isotherm studies were carried out with aqueous standard solutions of PCPs to ensure complete characterization of the performance. The studies demonstrate the high applicability and selectivity of the composites prepared, highlighting the performance of PVDF/DUT-52 MMM that poses uptakes up to 78% for those PCPs with higher affinity while observing detection limits for the entire method down to 0.03 μg·L–1. The PVDF/DUT-52 device allowed the detection of parabens and benzophenones in the samples, with PCPs found at concentrations of 1.9–24 mg·L–1.
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Research context

Composites

OpenAlex topics: Advanced Chemical Sensor Technologies · Analytical chemistry methods development · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratorio de Materiales para Análisis Químicos (MAT4ALL), Departamento de Química, Unidad Departamental de Química Analítica, Universidad de La Laguna (ULL), 38206 La Laguna, Tenerife, Spain

Unidad de Investigación de Bioanalítica y Medioambiente, Instituto Universitario de Enfermedades Tropicales y Salud Pública de Canarias, Universidad de La Laguna (ULL), 38206 La Laguna, Tenerife, Spain

Department of Chemistry, SRM Institute of Science and Technology, Kattankulathur, 603203 Chennai, Tamil Nadu, India

Laboratorio de Materiales para Análisis Químicos (MAT4ALL), Departamento de Química, Unidad Departamental de Química Inorgánica, Universidad de La Laguna (ULL), 38206 La Laguna, Tenerife, Spain

Technische Universität Dresden (TUD), Bergstrasse 66, 01069 Dresden, Germany

Funding

Fundaci?n CajaCanarias · Secretar?a de Estado de Investigaci?n, Desarrollo e Innovaci?n · Agencia Canaria de Investigaci?n, Innovaci?n y Sociedad de la Informaci?n

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