Light-Gated Modulation of Electronic Mobility of a Dihydropyrene-Based Photochromic Coordination Polymer
Source abstract
Abstract
-based two-dimensional coordination polymer (CP) having pyridine-functionalized photochromic dimethyldihydropyrene-cyclophanediene (DHP-CPD) π-switch. Both the coordination polymer and the organic photochromic core were characterized by single-crystal X-ray diffraction studies. The coordination polymer displayed an excellent conductance in the ON state of the switch in the closed form of DHP. Upon exposure to visible light, the π-switch in the CPD form loses its planarity, turning the switch OFF, which is reflected in the drastic reduction of the conductance. Exposure to UV light turns the switch back ON wherein the high electronic conductance of the polymer can be restored.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Photochromic and Fluorescence Chemistry · Porphyrin and Phthalocyanine Chemistry · Photoreceptor and optogenetics research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur, Nadia 741246, India
Funding
Science and Engineering Research Board · Indian Institute of Science Education and Research Kolkata · Council for Scientific and Industrial Research
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