Application of Advanced Vibrational Spectroscopy in Revealing Critical Chemical Processes and Phenomena of Electrochemical Energy Storage and Conversion

The future of the energy industry and green transportation critically relies on exploration of high-performance, reliable, low-cost, and environmentally friendly energy storage and conversion materials. Understanding the chemical processes and phenomena involved in electrochemical energy storage and conversion is the premise of a revolutionary materials discovery. In this article, we review the recent advancements of application of state-of-the-art vibrational spectroscopic techniques in unraveling the nature of electrochemical energy, including bulk energy storage, dynamics of liquid electrolytes, interfacial processes, etc. Technique-wise, the review covers a wide range of spectroscopic methods, including classic vibrational spectroscopy (direct infrared absorption and Raman scattering), external field enhanced spectroscopy (surface enhanced Raman and IR, tip enhanced Raman, and near-field IR), and two-photon techniques (2D infrared absorption, stimulated Raman, and vibrational sum frequency generation). Finally, we provide perspectives on future directions in refining vibrational spectroscopy to contribute to the research frontier of electrochemical energy storage and conversion.