Reversible Bond/Cation-Coupled Electron Transfer on Phenylenediamine-Based Rhodamine B and Its Application on Electrochromism
Source abstract
Abstract
A biomimetic system on reversible bond-coupled electron transfer (BCET) has been proposed and investigated in a switchable Rh–N molecule with redox active subunits. We discover that energy barrier of C–N bond breaking is reduced dramatically to less than 1/7 (from 40.4 to 5.5 kcal/mol), and 1/3 of the oxidation potential is simultaneously lowered (from 0.67 to 0.43 V) with the oxidation of Rh–N. The concept, cation-coupled electron transfer (CCET), is highly recommended by analyzing existing proton coupled electron transfer (PCET) and metal coupled electron transfer (MCET) along with aforementioned BCET, which have same characteristic of transferring positive charges, such as proton, metal ion, and organic cation. Molecular switch can be controlled directly by electricity through BCET process. Solid electrochromic device was fabricated with extremely high coloration efficiency (720 cm 2 /C), great reversibility (no degradation for 600 cycles), and quick respond time (30 ms).
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Conducting polymers and applications · Electrochemical Analysis and Applications · Organic Light-Emitting Diodes Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Lab of Supramolecular Structure and Materials, Jilin University, Changchun, 130012, P. R. China
College of Chemistry, Jilin University, Changchun, 130012, P. R. China
College of Electron Science and Engineering, Jilin University, Changchun 130012, P. R. China
Department of Chemistry and Pharmacy, Zhuhai College of Jilin University, Zhuhai, 519041, P. R. China
Funding
Ministry of Education of the People's Republic of China · National Natural Science Foundation of China
References (63)
Show source-provided references
1. 10.1021/acs.chemrev.5b0029810.1021/acs.chemrev.5b00298 ↗
2. 10.1021/cr068078710.1021/cr0680787 ↗
3. 10.1021/cr030731s10.1021/cr030731s ↗
4. 10.1021/cr050003010.1021/cr0500030 ↗
5. 10.1021/cr200177j10.1021/cr200177j ↗
6. 10.1021/cr100200310.1021/cr1002003 ↗
7. 10.1021/cr100070p10.1021/cr100070p ↗
8. 10.1016/j.ccr.2009.10.02010.1016/j.ccr.2009.10.020 ↗
9. 10.1021/ja410406e10.1021/ja410406e ↗
10. 10.1039/c3tc30769g10.1039/c3tc30769g ↗
11. 10.1039/c3cc44924f10.1039/c3cc44924f ↗
12. 10.1002/poc.109610.1002/poc.1096 ↗
13. 10.1021/jo702104j10.1021/jo702104j ↗
14. 10.1021/ja015526d10.1021/ja015526d ↗
15. 10.1021/ja029139v10.1021/ja029139v ↗
16. 10.1021/ja046125b10.1021/ja046125b ↗
17. 10.1021/ar980014y10.1021/ar980014y ↗
18. 10.1021/jo102086f10.1021/jo102086f ↗
19. 10.1021/jo202418d10.1021/jo202418d ↗
20. 10.1021/jo400461c10.1021/jo400461c ↗
21. 10.1021/ja500087m10.1021/ja500087m ↗
22. 10.1021/ja406626710.1021/ja4066267 ↗
23. 10.1021/ja043256410.1021/ja0432564 ↗
24. 10.1039/b911932a10.1039/b911932a ↗
25. 10.1139/v03-07310.1139/v03-073 ↗
26. 10.1021/ja002274s10.1021/ja002274s ↗
27. 10.1021/ja962291a10.1021/ja962291a ↗
28. 10.1021/ma021679p10.1021/ma021679p ↗
29. 10.1021/jp505166a10.1021/jp505166a ↗
30. 10.1021/acs.jpclett.5b0222010.1021/acs.jpclett.5b02220 ↗
31. 10.1021/cr068070x10.1021/cr068070x ↗
32. 10.1021/jp100079q10.1021/jp100079q ↗
33. 10.1021/ja411689w10.1021/ja411689w ↗
34. 10.1039/C3OB42089B10.1039/C3OB42089B ↗
35. 10.1021/ja511499p10.1021/ja511499p ↗
36. 10.1021/j100400a02110.1021/j100400a021 ↗
37. 10.1021/ed060p70210.1021/ed060p702 ↗
38. 10.1016/j.synthmet.2006.03.00110.1016/j.synthmet.2006.03.001 ↗
39. 10.1016/S0013-4686(00)00691-510.1016/S0013-4686(00)00691-5 ↗
40. 10.1021/cr940053x10.1021/cr940053x ↗
41. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J.Gaussian 09, revisionA.02;Gaussian, Inc.:Wallingford, CT, 2009.
42. 10.1016/S0022-0728(79)80075-310.1016/S0022-0728(79)80075-3 ↗
43. 10.1016/j.displa.2005.03.00310.1016/j.displa.2005.03.003 ↗
44. 10.1021/cr900129a10.1021/cr900129a ↗
45. 10.1016/j.mattod.2015.11.00710.1016/j.mattod.2015.11.007 ↗
46. 10.1039/C6TC03542F10.1039/C6TC03542F ↗
47. 10.1002/adfm.20160181910.1002/adfm.201601819 ↗
48. 10.1039/C5EE03160E10.1039/C5EE03160E ↗
49. 10.1021/acsami.6b1010310.1021/acsami.6b10103 ↗
50. 10.1021/acsami.6b0191110.1021/acsami.6b01911 ↗
51. 10.1039/C6RA13951E10.1039/C6RA13951E ↗
52. 10.1002/adma.20160449110.1002/adma.201604491 ↗
53. 10.1038/nmat473410.1038/nmat4734 ↗
54. 10.1002/adfm.20150052710.1002/adfm.201500527 ↗
55. 10.1002/adfm.20150263810.1002/adfm.201502638 ↗
56. 10.1039/C5SC03727A10.1039/C5SC03727A ↗
57. 10.1021/acsami.6b1165710.1021/acsami.6b11657 ↗
58. 10.1021/acs.jpcc.6b0882010.1021/acs.jpcc.6b08820 ↗
59. 10.1002/smll.20160097910.1002/smll.201600979 ↗
60. 10.1038/lsa.2015.2210.1038/lsa.2015.22 ↗
61. 10.1016/j.jelechem.2010.11.00410.1016/j.jelechem.2010.11.004 ↗
62. 10.1016/j.electacta.2012.09.01910.1016/j.electacta.2012.09.019 ↗
63. 10.1016/j.electacta.2017.02.04610.1016/j.electacta.2017.02.046 ↗