journal article·2016-05-11

Hollow Casein-Based Polymeric Nanospheres for Opaque Coatings

Fan Zhang, Jianzhong Ma, Qunna Xu, Jianhua Zhou, Demetra Simion, Gaidău Carmen, John Wang, Yunqi Li

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Abstract

Casein-based hollow polymeric sphere were fabricated through emulsifier-free polymerization coupled with alkali swelling approach. Hollow structure and nanoscale size of casein-based polymeric spheres were verified by TEM, AFM, SEM, and UV-vis spectra. The as-obtained hollow spheres were proved exhibiting superior opaque characteristic. Through adjusting the structural parameters, for example, MAA usages and MAA content in seed to core, sphere film showed tunable visible-light transmittance and antiultraviolet property. The formation mechanism of casein-based hollow sphere has been discussed in depth. Worth mentioning, the resultant hollow polymeric sphere can easily form films itself at room temperature, which would open a new possibility of designing opaque coatings in several fields, such as leather, packaging, paper making, biomedical, and special indoor coating applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Polymer Surface Interaction Studies · Quantum Dots Synthesis And Properties · Nanomaterials and Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Resource and Environment, Shaanxi University of Science and Technology, Xi’an 710021, Shaanxi Province PR China

Shaanxi Research Institute of Agricultural Products Processing Technology, Xi’an 710021, Shaanxi Province PR China

R&D National institute for Textile and Leather-Division Leather and Footwear Research Institute, Bucharest 031215, Romania

Department of Materials Science and Engineering, National University of Singapore, Singapore 117574, Singapore

Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, PR China

Funding

National Natural Science Foundation of China · Shaanxi Province · Education Department of Shaanxi Provincial Government

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