DataVXACS Applied Materials & InterfacesPaper
journal article·2018-08-08

Low-Pressure Flow Chemistry of CuAAC Click Reaction Catalyzed by Nanoporous AuCu Membrane

Jiangwei Wen, Kun Wu, Dali Yang, Jun Tian, Zhiyuan Huang, Alexander S. Filatov, Aiwen Lei, Xiao-Min Lin

ACS Applied Materials & Interfaces· Volume 10· Issue 31
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Source abstract

Abstract

Click chemistry has been widely used in bioconjugation, polymer synthesis, and the development of new anticancer drugs. Here, we report a nanoporous membrane made of AuCu alloy nanowires, which can effectively catalyze copper(I)-catalyzed 1,3-dipolar cycloaddition between azide and terminal alkyne (CuAAC) in flow condition with pressure less than one bar. Comparison studies of the nanowires before and after the reaction using X-ray photoelectron spectroscopy reveal Cu(0) and Cu(I) are main species that promote the reaction. This simple strategy can be used to synthesize a variety of compounds with triazole linkage and extended to gram level chemical production.
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Research context

Metals & alloysPolymersNanomaterialsCatalysis & surfaces

OpenAlex topics: Advanced biosensing and bioanalysis techniques · Monoclonal and Polyclonal Antibodies Research · Innovative Microfluidic and Catalytic Techniques Innovation

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Affiliations

The Institute for Advanced Studies (IAS), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, P. R. China

Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States

Department of Chemistry, The University of Chicago, 929 East 57th Street, Chicago, Illinois 60637, United States

Funding

Ministry of Science and Technology of the People's Republic of China · Basic Energy Sciences · National Natural Science Foundation of China

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