journal article·2016-06-15Open access

Single Walled Carbon Nanohorns as Catalytic Counter Electrodes for Co(III)/(II) Electron Mediators in Dye Sensitized Cells

Stefano Carli, Laura Casarin, Zois Syrgiannis, Rita Boaretto, Elisabetta Benazzi, Stefano Caramori, Maurizio Prato, Carlo Alberto Bignozzi

Abstract

The electrochemical properties of both pristine single walled carbon nanohorns (SWCNHS) and their chemically oxidized form (ox-SWCNHS) spray coated onto fluorine doped SnO2 (FTO) were investigated in the framework of the fabrication of cobalt based transparent dye sensitized solar cells (DSSCs). These new nanocarbon substrates, evaluated in conjunction with the Co(bpy)3(2+/3+) (bpy = 2,2'-bipyridine) redox mediator, are endowed with excellent electrocatalytic properties, ease of fabrication, and very promising stability and display a great potential for replacing the best noble metal and conductive polymer catalytic materials in the building of semitransparent counter electrodes in new generation photoelectrochemical devices.
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Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Electrochemical sensors and biosensors · Electrochemical Analysis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical and Pharmaceutical Sciences, University of Ferrara, Via Fossato di Mortara 17, 44121 Ferrara, Italy

Department of Chemical and Pharmaceutical Sciences, University of Trieste, Piazzale Europa 1, 34127 Trieste, Italy

Carbon Nanobiotechnology Laboratory, CIC biomaGUNE, Paseo de Miramón 182, 20009 Donostia-San Sebastian, Spain

Basque Fdn Sci, Ikerbasque, Bilbao 48013, Spain

Funding

Ministero dell’Istruzione, dell’Università e della Ricerca

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