High Energy Storage Performance of PZO/PTO Multilayers via Interface Engineering
Source abstract
Abstract
Antiferroelectric thin-film capacitors with ultralow remanent polarization and fast discharge speed have attracted extensive attention for energy storage applications. A multilayer heterostructure is considered to be an efficient approach to enhance the breakdown strength and improve the functionality. Here, we report a high-performance multilayer heterostructure (PbZrO 3 /PbTiO 3 ) n with a maximum recoverable energy storage density of 36.4 J/cm 3 due to its high electric breakdown strength (2.9 MV/cm) through the heterostructure strategy. The positive effect of interfacial blockage and the negative effect of local strain defects competitively affect the breakdown strength, showing an inflection point at n = 3. The atomic-scale characterizations reveal the underlying microstructure mechanism of the interplay between the heterointerface dislocations and the decreased energy storage performance. This work offers the potential of well-designed multilayers with high energy storage performance through heterostructure engineering.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Multiferroics and related materials · Ferroelectric and Negative Capacitance Devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Science, School of Physics and Electronic Science, East China Normal University, Shanghai200241, People’s Republic of China
Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong, Wollongong2522, New South Wales, Australia
The Key Lab of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai200050, People’s Republic of China
Funding
Ministry of Science and Technology of the People's Republic of China · Natural Science Foundation of Chongqing · National Natural Science Foundation of China
References (52)
Show source-provided references
1. 10.1126/science.aaw810910.1126/science.aaw8109 ↗
2. 10.1038/s41563-022-01274-610.1038/s41563-022-01274-6 ↗
3. 10.1016/j.pmatsci.2018.12.00510.1016/j.pmatsci.2018.12.005 ↗
4. 10.1002/adfm.20180150410.1002/adfm.201801504 ↗
5. 10.1002/adma.20180215510.1002/adma.201802155 ↗
6. 10.1126/science.abi768710.1126/science.abi7687 ↗
7. 10.1002/adma.20160172710.1002/adma.201601727 ↗
8. 10.1002/aelm.20190069810.1002/aelm.201900698 ↗
9. 10.1021/acsnano.0c0079110.1021/acsnano.0c00791 ↗
10. 10.1002/adfm.20200362210.1002/adfm.202003622 ↗
11. 10.1016/j.nanoen.2018.07.00710.1016/j.nanoen.2018.07.007 ↗
12. 10.1021/acsami.0c0556010.1021/acsami.0c05560 ↗
13. 10.1002/adma.20160442710.1002/adma.201604427 ↗
14. 10.1016/j.ceramint.2019.06.26610.1016/j.ceramint.2019.06.266 ↗
15. 10.3390/nano1108214110.3390/nano11082141 ↗
16. 10.1111/jace.1487610.1111/jace.14876 ↗
17. 10.1002/aenm.20220051710.1002/aenm.202200517 ↗
18. 10.20517/microstructures.2022.3810.20517/microstructures.2022.38 ↗
19. 10.1088/0022-3727/32/1/00110.1088/0022-3727/32/1/001 ↗
20. 10.1016/j.ceramint.2018.08.05910.1016/j.ceramint.2018.08.059 ↗
21. 10.1016/j.pmatsci.2014.01.00210.1016/j.pmatsci.2014.01.002 ↗
22. 10.1002/advs.20210222110.1002/advs.202102221 ↗
23. 10.1016/j.tsf.2004.07.02410.1016/j.tsf.2004.07.024 ↗
24. 10.1063/1.11670510.1063/1.116705 ↗
25. 10.1007/s10854-016-5114-010.1007/s10854-016-5114-0 ↗
26. 10.1016/j.materresbull.2016.08.00510.1016/j.materresbull.2016.08.005 ↗
27. 10.1021/acsami.5b0878610.1021/acsami.5b08786 ↗
28. 10.1557/jmr.2012.12410.1557/jmr.2012.124 ↗
29. 10.1016/j.ceramint.2012.10.12410.1016/j.ceramint.2012.10.124 ↗
30. 10.1063/1.292823010.1063/1.2928230 ↗
31. 10.1111/j.1551-2916.2009.03015.x10.1111/j.1551-2916.2009.03015.x ↗
32. 10.1021/acsami.2c0545510.1021/acsami.2c05455 ↗
33. 10.1016/j.tsf.2018.05.04810.1016/j.tsf.2018.05.048 ↗
34. 10.1016/j.ceramint.2013.10.11010.1016/j.ceramint.2013.10.110 ↗
35. 10.1039/C8QI00487K10.1039/C8QI00487K ↗
36. 10.1016/j.ssc.2015.06.01710.1016/j.ssc.2015.06.017 ↗
37. 10.1016/j.jeurceramsoc.2019.07.02410.1016/j.jeurceramsoc.2019.07.024 ↗
38. 10.1063/1.347382110.1063/1.3473821 ↗
39. 10.1063/1.490239610.1063/1.4902396 ↗
40. Li D. X. · Microstructures · 2023 · 3 · 202300710.20517/microstructures.2022.27 ↗
41. Reyes-Lillo S. E. · Phys. Rev. B · 2013 · 88 · 18010210.1103/PhysRevB.88.180102 ↗
42. 10.1063/5.002959910.1063/5.0029599 ↗
43. 10.1063/1.352592610.1063/1.3525926 ↗
44. 10.1021/nl304229k10.1021/nl304229k ↗
45. 10.1038/nmat105710.1038/nmat1057 ↗
46. 10.1016/j.scriptamat.2020.11.00910.1016/j.scriptamat.2020.11.009 ↗
47. 10.1038/ncomms1599410.1038/ncomms15994 ↗
48. 10.1063/1.172830010.1063/1.1728300 ↗
49. 10.1080/0141861990821429410.1080/01418619908214294 ↗
50. 10.1063/1.192257910.1063/1.1922579 ↗
51. 10.1063/1.178889410.1063/1.1788894 ↗
52. 10.1021/acs.nanolett.9b0050610.1021/acs.nanolett.9b00506 ↗