journal article·2022-04-27

“Brush-like” Amphiphilic Polymer for Environmental Adaptive Coating

Zhengfeng Ma, Yizhe Liu, Kai Feng, Jianteng Wei, Jianxi Liu, Yang Wu, Xiaowei Pei, Bo Yu, Meirong Cai, Feng Zhou

ACS Applied Materials & Interfaces· Volume 14· Issue 16
Publisher page

Abstract

Multiple functional coating is urgently needed in complex service surroundings to meet various requirements. In this work, a brush-like amphiphilic copolymer of poly methacryloxyethyl dimethyl butyl ammonium bromide-polydimethylsiloxane (pMDBAB-PDMS) was synthesized to construct an environment-adaptive multifunctional coating based on the copolymer via the UV-curing method. The special molecule chains of the copolymer assembled predominately on the coating surface in different surroundings, which rendered the surface with various functions. In water-rich surroundings, the hydrophilic quaternary ammonium groups in the coating endow the coating surface with antifogging, oleophobicity underwater, self-cleaning, antibacteria, triboelectric resistance, and super lubrication properties. In dry air surroundings, the long, flexible, low surface energy molecular PDMS chains tend to distribute on the top of the coating surface, which gives a low friction coefficient and antioil properties. This work presents a strategy to construct environmental adaptive coating that has an important application prospect in the field of optical lens.
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Research context

OpenAlex topics: Polymer Surface Interaction Studies · Surface Modification and Superhydrophobicity · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu 730000, PR China

Shandong Laboratory of Advanced Materials and Green Manufacture, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering, Yantai, Shandong 264006, PR China

Qingdao Center of Resource Chemistry and New Materials, Qingdao, Shandong 266100, PR China

State Key Laboratory of Solidification Processing, Centre of Advanced Lubrication and Seal Materials, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, PR China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shandong Province · Chinese Academy of Sciences · LICP Cooperation Foundation for Young Scholars · Young Talents Support Plan of Gansu Association for Science and Technology · NSAF

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