journal article·2021-12-08

A New Co-Free Ni-Rich LiNi0.8Fe0.1Mn0.1O2 Cathode for Low-Cost Li-Ion Batteries

Yukun Xi, Mingjun Wang, Le Xu, Hirbod Maleki Kheimeh Sari, Wenbin Li, Junhua Hu, Yanyan Cao, Liping Chen, Linzhe Wang, Xiaohua Pu, Jingjing Wang, Yikun Bai, Xingjiang Liu, Xifei Li

ACS Applied Materials & Interfaces· Volume 13· Issue 48
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Abstract

In recent years, with the rapid development of electric vehicles, the ever-fluctuating cobalt price has become a decisive constraint on the supply chain of the lithium-ion (Li-ion) battery industry. To address these challenges, a new and unreported cobalt-free (Co-free) material with a general formula of LiNi0.8Fe0.1Mn0.1O2 (NFM) is introduced. This Co-free material is synthesized via the coprecipitation method and examined by using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and density functional theory (DFT) to investigate the morphological, crystal-structure, and electrochemical properties. The NFM cathode can deliver a specific capacity of 202.6 mA h g–1 (0.1C, 3.0–4.5 V), a specific energy capacity of 798.8 W h kg–1 in material level (0.1C, 3.0–4.5 V), a reasonable rate capability, and a stable cycling performance (81.1% discharge capacity retention after 150 cycles at 10C, 3.0–4.3 V). Although the research on this subject is still in its early stage, the capability of this novel cathode material as a practical candidate for applications in next-generation Co-free lithium-ion batteries (LIBs) is highlighted in this study.
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Research context

OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Automation and Information Engineering, Xi’an University of Technology, Xi’an, Shaanxi710048, P. R. China

Xi’an Key Laboratory of New Energy Materials and Devices, Institute of Advanced Electrochemical Energy, School of Materials Science and Engineering, Xi’an University of Technology, Xi’an, Shaanxi710048, P. R. China

Shaanxi International Joint Research Center of Surface Technology for Energy Storage Materials, Xi’an, Shaanxi710048, P. R. China

Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai200237, P. R. China

Center for International Cooperation on Designer Low-Carbon & Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou, Henan450001, P. R. China

Science and Technology on Power Sources Laboratory, Tianjin Institute of Power Sources, Tianjin300384, P. R. China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Shaanxi Province · Natural Science Foundation of Qinghai Province · Joint Foundation of Shaanxi · Xi???an Science and Technology Project · Natural Science Basic Research Program of Shaanxi · National Key Laboratory

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