Paintable Hybrids with Thermally Stable Dual Emission Composed of Tetraphenylethene-Integrated POSS and MEH-PPV for Heat-Resistant White-Light Luminophores

Thermally stable dual emission followed by white-light luminescence from hybrid materials is reported. Hybrid films were prepared with a spin-coating method with the mixture solution containing tetraphenylethene (TPE)-integrated polyhedral oligomeric silsesquioxane (POSS) and poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylene vinylene] (MEH-PPV). TPE-tethered POSS (TPE-POSS) showed high compatibility with MEH-PPV. Therefore, homogeneous films with variable concentrations of TPE-POSS were obtained. Owing to good dispersion of rigid silica cubes into matrices, POSS-containing films demonstrated high thermal stability toward molecular rearrangement by annealing as well as pyrolysis, similar to conventional polymer hybrids. Furthermore, it was found that TPE-POSS was able to enhance emission efficiencies, probably by suppressing chain aggregation. By modulating introduction ratios of TPE-POSS, dual-emission properties followed by white-light luminescence composed of cyan and orange emissions from TPE-POSS and MEH-PPV, respectively, were accomplished. It should be noted that these color balances can be preserved even in the high-temperature region (425 K). Finally, white-light luminescent materials with thermal durability were obtained.