Superhydrophobic Polydimethylsiloxane via Nanocontact Molding of Solvent Crystallized Polycarbonate: Optimized Fabrication, Mechanistic Investigation, and Application Potential

Herein, we describe a benchtop protocol to create superhydrophobic polydimethylsiloxane (PDMS) via nanocontact molding of polycarbonate (PC) that was crystallized by controlled solvent treatment. The crystallized PC chains rearrange into a network of spherulites (spherical semicrystalline domains); the overall surface is rough on the micrometer-scale, while the spherulites themselves consist of nanoscale features. It was confirmed via conventional spectroscopic and high-resolution microscopic investigation that such hierarchical roughness is key to the development of superhydrophobic PC and the substantial enhancement upon PDMS molding. Thus, the prepared PDMS surface has excellent superhydrophobicity with an optimized contact angle of 172 ± 1° and a sliding angle of <1°, superior to those prepared from more elaborate techniques, such as plasma sputtering and laser etching. More importantly, the knowledge acquired regarding the structural transition and superhydrophobicity development would be beneficial to engineering and evaluating templates for many other polymeric nanostructures and functional surfaces.