Loading across the Periodic Table: Introducing 14 Different Metal Ions To Enhance Metal–Organic Framework Performance
Source abstract
Abstract
Loading metal guests within metal–organic frameworks (MOFs) via secondary functional groups is a promising route for introducing or enhancing MOF performance in various applications. In this work, 14 metal ions (Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Zn2+, Co2+, Mn2+, Ag+, Cd2+, La3+, In3+, and Pb2+) have been successfully introduced within the MIL-121 MOF using a cost-efficient route involving free carboxylic groups on the linker. The local and long-range structure of the metal-loaded MOFs is characterized using multinuclear solid-state NMR and X-ray diffraction methods. Li/Mg/Ca-loaded MIL-121 and Ag nanoparticle-loaded MIL-121 exhibit enhanced H2 and CO2 adsorption; Ag nanoparticle-loaded MIL-121 also demonstrates remarkable catalytic activity in the reduction of 4-nitrophenol.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Chemical Synthesis and Characterization · Zeolite Catalysis and Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, University of Western Ontario, London, Ontario N6A 5B7, Canada
Institute of Functional Nano & Soft Materials Laboratory (FUNSOM) & Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Jiangsu 215123, P. R. China
Department of Chemistry, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada
Funding
Natural Sciences and Engineering Research Council of Canada · National Natural Science Foundation of China · Priority Acadamic Program Development of Jiangsu Higher Education Institutions
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