pH-Responsive Dual-Emitting Hydroxypropyl Methylcellulose-Based Material Containing Fluorescein Isothiocyanate and CaAl₂O₄:Eu²⁺,Dy³⁺ Phosphors

Herein, we prepared a dual-emitting cellulose film with pH response, which offers high transparency, good flexibility, and intense thermal stability. The color of the fluorescent film that changes from green to blue-green to cyan was achieved by covalently attaching organic dye fluorescein isothiocyanate (FITC), inorganic pigment NH2-CaAl2O4:Eu2+,Dy3+ (NH2-CAO), and organic–inorganic fluorescence species onto hydroxypropyl methylcellulose (HMPC) chains, respectively. Benefiting from the “anchoring” and “dilution” effects of the HMPC skeleton, HPMC-FITC and HPMC@NH2-CAO fluorescent solutions and solid-state films emit green and blue-green fluorescence at 535 and 480 nm, respectively. The obtained pH-responsive cellulose-based dual-emitting film can continuously emit cyan light at the two emission peaks of 480 and 535 nm for a long time and exhibits strong fluorescence intensity under exceedingly alkaline conditions. Moreover, the HPMC-based fluorescent solution coated on glass and fabric substrate shows strong fluorescence under 365 nm UV light stimulation. Compared with the existing cellulose-based fluorescent films, this work expands the emission wavelength range of cellulose-based fluorescent films and prolongs the luminescent time of environment-responsive fluorescent films. This provides a new way to prepare intelligent color-changing fabric-coating materials and sensitive pH sensors based on biomass.