journal article·2020-06-17

A Dendrite-free Na–Na2S–Carbon Hybrid toward a Highly Stable and Superior Sodium Metal Anode

Weiming Wu, Shaogang Hou, Changsong Zhang, Linsen Zhang

ACS Applied Materials & Interfaces· Volume 12· Issue 24
Publisher page

Abstract

An effective method to fabricate a dendrite-free Na–Na2S–carbon hybrid anode is developed by immersing sulfur-doped carbon paper into molten sodium with common tissue paper as the starting material. The as-obtained hybrid anode displays much decreased nucleation and mass-transfer-controlled overpotentials for sodium plating, and a low and stable voltage hysteresis of ∼150 mV is obtained under a current density of 4 mA cm–2. It provides a dendrite-free sodium-based anode with superior rate performance and long-term stability. Furthermore, it provides an effective avenue to alleviate the growth of dendrites and lower the overpotentials for other kinds of metal-based electrodes.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Inorganic Chemistry and Materials

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Affiliations

School of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China

School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China

Funding

Anyang Institute of Technology · Education Department of Henan Province · National Natural Science Foundation of China · National Research Program for Key Issues in Air Pollution Control of China

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