journal article·2018-04-18

New Ablation-Resistant Material Candidate for Hypersonic Applications: Synthesis, Composition, and Oxidation Resistance of HfIr3-Based Solid Solution

Victor V. Lozanov, Natalya I. Baklanova, Natalia V. Bulina, Anatoly T. Titov

ACS Applied Materials & Interfaces· Volume 10· Issue 15
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Abstract

The peculiarities of the solid-state interaction in the HfC–Ir system have been studied within the 1000–1600 °C temperature range using a set of modern analytical techniques. It was stated that the interaction of HfC with iridium becomes noticeable at temperatures as low as 1000–1100 °C and results in the formation of HfIr3-based substitutional solid solution. The homogeneity range of the HfIr3±x phase was evaluated and refined as HfIr2.43–HfIr3.36. The durability of the HfIr3-based system under extreme environmental conditions was studied. It was shown that the HfIr3-based material displays excellent ablation resistance under extreme environmental conditions. The benefits of the new designed material result from its relative oxygen impermeability and special microstructure similar to superalloys. The results obtained in this work allow us to consider HfIr3 as a very promising candidate for extreme applications.
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Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Advanced ceramic materials synthesis · Boron and Carbon Nanomaterials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Solid State Chemistry and Mechanochemistry SB RAS, Kutateladze Street 18, Novosibirsk 630128, Russian Federation

V. S. Sobolev Institute of Geology and Mineralogy SB RAS, Koptyug Avenue 3, Novosibirsk 630090, Russian Federation

Funding

Siberian Branch, Russian Academy of Sciences · Russian Foundation for Basic Research

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