journal article·2022-10-12

CoZn Nanoparticles@Hollow Carbon Tubes Enabled High-Performance Potassium Metal Batteries

Guangzeng Cheng, Shuai Liu, Xingjie Wang, Xurui Li, Yunxing Su, Jing Shi, Minghua Huang, Zhicheng Shi, Huanlei Wang, Zhenhua Yan

ACS Applied Materials & Interfaces· Volume 14· Issue 40
Publisher page

Abstract

Potassium-metal batteries (PMBs) are attractive candidates for low-cost and large-scale energy storage systems due to the abundance of potassium. However, its application is hampered by large volume change and serious dendrite growth. Herein, a CoZn semicoherent structure nanoparticle-embedded nitrogen-doped hollow carbon tube (CoZn@HCT) electrode is prepared via coaxial electrospinning. Due to the high potassiophilic CoZn semicoherent structure nanoparticles and large potassium metal storage space, the free-standing CoZn@HCT host for K metal exhibits uniform K nucleation and stable plating/stripping (stable cycling 1000 h at 1 mA cm–2 with 1 mA h cm–2). Furthermore, enhanced electrochemical performance with good cycling stability and rate capability is achieved in (CoZn@HCT@K||PTCDA) full batteries. Our results highlight a promising strategy for dendrite-free K metal anodes and high-performance PMBs.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

Funding

Ocean University of China · Central University Basic Research Fund of China · National Natural Science Foundation of China · Natural Science Foundation of Shandong Province · Key Laboratory of Advanced Energy Materials Chemistry

References (41)

Show source-provided references
1. 10.1002/adma.20190673910.1002/adma.201906739 ↗
2. 10.1016/j.esci.2021.12.00110.1016/j.esci.2021.12.001 ↗
3. 10.1002/adfm.20180293810.1002/adfm.201802938 ↗
4. 10.1016/j.esci.2021.09.00310.1016/j.esci.2021.09.003 ↗
5. 10.1126/sciadv.aav741210.1126/sciadv.aav7412 ↗
6. 10.1021/acs.chemrev.1c0083810.1021/acs.chemrev.1c00838 ↗
7. 10.1002/adma.20200290810.1002/adma.202002908 ↗
8. 10.1002/tcr.20170005710.1002/tcr.201700057 ↗
9. 10.1016/j.elecom.2015.09.00210.1016/j.elecom.2015.09.002 ↗
10. 10.1039/c6cc10280h10.1039/c6cc10280h ↗
11. 10.1016/j.ensm.2022.05.02410.1016/j.ensm.2022.05.024 ↗
12. 10.1002/adma.20170051910.1002/adma.201700519 ↗
13. 10.1038/s41467-018-03466-810.1038/s41467-018-03466-8 ↗
14. 10.1021/acsami.5b0803710.1021/acsami.5b08037 ↗
15. 10.1002/adma.20160263310.1002/adma.201602633 ↗
16. 10.1016/j.esci.2022.03.00110.1016/j.esci.2022.03.001 ↗
17. 10.1016/j.esci.2022.06.00210.1016/j.esci.2022.06.002 ↗
18. 10.1002/anie.20180411510.1002/anie.201804115 ↗
19. 10.1021/acs.jpclett.9b0071110.1021/acs.jpclett.9b00711 ↗
20. 10.1016/j.cej.2021.12859710.1016/j.cej.2021.128597 ↗
21. 10.1016/j.ensm.2020.05.01810.1016/j.ensm.2020.05.018 ↗
22. 10.1002/adma.20190673510.1002/adma.201906735 ↗
23. 10.1016/j.cej.2020.12584310.1016/j.cej.2020.125843 ↗
24. 10.1021/acsnano.1c0549710.1021/acsnano.1c05497 ↗
25. 10.1002/aenm.20190142710.1002/aenm.201901427 ↗
26. 10.1039/c9ta14226f10.1039/c9ta14226f ↗
27. 10.1021/acsaem.1c0100210.1021/acsaem.1c01002 ↗
28. 10.1021/jacs.7b1158910.1021/jacs.7b11589 ↗
29. 10.1016/j.chempr.2016.06.00110.1016/j.chempr.2016.06.001 ↗
30. 10.1016/j.carbon.2015.06.07610.1016/j.carbon.2015.06.076 ↗
31. 10.1002/adma.20100411010.1002/adma.201004110 ↗
32. 10.1016/j.jpowsour.2017.04.02910.1016/j.jpowsour.2017.04.029 ↗
33. 10.1016/j.ensm.2020.02.00410.1016/j.ensm.2020.02.004 ↗
34. 10.1016/j.cej.2019.12245710.1016/j.cej.2019.122457 ↗
35. 10.1016/j.jallcom.2021.15926210.1016/j.jallcom.2021.159262 ↗
36. 10.1039/d1ta09070d10.1039/d1ta09070d ↗
37. 10.1016/j.joule.2017.11.00410.1016/j.joule.2017.11.004 ↗
38. 10.1021/acsami.1c0218610.1021/acsami.1c02186 ↗
39. 10.1039/c8ta06724d10.1039/c8ta06724d ↗
40. 10.1039/c8ta09960j10.1039/c8ta09960j ↗
41. 10.1016/j.carbon.2022.07.03710.1016/j.carbon.2022.07.037 ↗